Search
Use the search bar or filters below to find any TAPPI product or publication.
Filters
Content Type
Publications
Level of Knowledge
Committees
Collections
Journal articles
Magazine articles
Lignin-based resins for kraft paper applications, TAPPI Journal November 2019
ABSTRACT: We investigated miscanthus (MS) and willow (W) lignin-furfural based resins as potential reinforce-ment agents on softwood and hardwood kraft paper. These resins might be sustainable alternatives to the commercial phenolformaldehyde (PF) resins. Phenol is a petrochemical product and formaldehyde has been classified as a carcinogen by the U.S. Environmental Protection Agency. The lignin used in this study was derived from hot water extraction (160ºC, 2 h) of MS and W biomass, and may be considered sulfur-free. These biorefinery lignins were characterized for their chemical composition and inherent properties via wet chemistry and instrumental techniques. The resin blends (MS-resin and W-resin) were characterized for their molecular weight, thermal behavior, and mechanical properties. Mechanical properties were measured by the resin’s ability to reinforce softwood and hard-wood kraft papers. The effect of adding hexamethylenetetramine (HMTA), a curing agent, to the resin was also examined. Mixtures of PF and lignin-based resins were investigated to further explore ways to reduce use of non-renewables, phenol, and carcinogenic formaldehyde. The results show that lignin-based resins have the potential to replace PF resins in kraft paper applications. For softwood paper, the highest strength was achieved using W-resin, without HMTA (2.5 times greater than PF with HMTA). For hardwood paper, MS-resin with HMTA gave the highest strength (2.3 times higher than PF with HMTA). The lignin-based resins, without HMTA, also yielded mechanical properties comparable to PF with HMTA.
Journal articles
Magazine articles
Determining operating variables that impact internal fiber bonding using Wedge statistical analysis
ABSTRACT: In this study, Wedge statistical analysis tools were used to collect, collate, clean up, plot, and analyze several years of operational data from a commercial paper machine. The z-direction tensile (ZDT) and Scott Bond tests were chosen as representative of fiber bond strength. After analyzing thousands of operational parameters, the ones with the most significant impact upon ZDT involved starch application method, starch penetration, and the amount of starch applied. Scott bond was found to be significantly impacted by formation and refining. Final calendering of the paper web has also shown an impact on internal fiber bonding.
Journal articles
Magazine articles
Effects of tissue additives on copy paper forming and properties, TAPPI Journal February 2024
ABSTRACT: Laboratory tests were conducted in an effort to determine the effects on paper machine process attributes and the properties of paper made from recycled copy paper furnish upon the addition of chemical agents that are commonly used in the production of hygiene tissue products. Due to continuing growth in tissue and towel grades of paper, such agents are experiencing greater usage. Charge titration test results revealed that certain dry strength agents associated with tissue manufacturing have the potential to shift the balance of charge in papermaking furnish to less negative or even positive values. Creping adhesive was found to contribute to fine particle retention, especially when present at relatively high levels. Release aid and a polyacrylate dispersant had the opposite effect. Low addition levels of both a creping adhesive and a debonding agent surprisingly increased a wide range of strength attributes of paper handsheets in comparison to sheets prepared from unaltered recycled copy paper furnish. The debonding agent decreased paper strength at higher levels of addition. Such effects appear to depend not only on the expected effects of agents themselves, but also on how they affect the charge balance of the wet-end system.
Journal articles
Magazine articles
Pareto-based design of experiments for identifying and comparing optimum sealing parameters of heat sealing applications in packaging machines, TAPPI Journal June 2023
ABSTRACT: Sealing is one of the most important process steps in industrial packaging, because the sealed seam is the most sensitive section of a package in terms of quality. For this reason, a major focus in flexible packaging is the sealing process, and among this, heat sealing is the most frequently used technology. In detail, applications of heat sealing processes are confronted with four conflicting objectives: increasing seam quality, reducing dwell time, reducing sealing temperature, and increasing process robustness towards varying conditions. Typical problems, such as identification of the optimum process parameters or selection of the most appropriate packaging film, are subject to these conflicting objectives.This paper presents a recently published design of experiments for characterizing and comparing heat sealing properties of packaging films based on a multi-objective optimization algorithm. The approach provides easy-to-read charts showing all optimum sealing parameters with regard to the four essential objectives of heat sealing: seam quality, dwell time, sealing temperature, and process robustness. Three case studies show exemplary applications of the new approach: 1) analyzing transport damages of beverage powder packages; 2) identifying and comparing optimum sealing parameter of a standard, mono-material, and fiber based packaging film regarding tightness and visual properties of the produced sachets; and 3) analyzing the effect of additional aluminum layers on sealing characteristics regarding hot-tack.The new design of experiments may provide the basis of a standard test method for the identification of optimal sealing parameters in the heat sealing processes.
Journal articles
Magazine articles
Impact of different calendering strategies on barrier coating pickup, TAPPI Journal November 2023
ABSTRACT: Paper was pre-calendered in a pilot scale configuration with a traditional soft nip calender and a metal belt calender. All calendering strategies reduced surface roughness and permeability of the samples, but different strategies affected the surface roughness and permeability differently. The metal belt calender seemed to have a larger effect on the large-scale variations compared to the soft nip calender. Six test points from the pilot calendered papers were chosen for laboratory coating studies. Uncalendered paper was included as reference samples. The calendered samples and the reference were pre-coated with a regular pigmented coating consisting of a ground calcium carbonate (GCC) pigment and a styrene acrylate (SA) latex. Both uncoated and pre-coated substrates were barrier coated with a polyvinyl alcohol (PVOH) in one and two layers. The coating pickup was determined gravimetrically, and the barrier properties were evaluated with TAPPI Standard Test Method T 454 grease resistance test. All samples needed two PVOH coating layers to form a grease barrier. The uncalendered sheets showed the best results with one coating layer, but this was at the expense of a higher coating pickup compared to the calendered sheets. The barrier coating pickup could be reduced by a combination of high temperature metal belt calendering and pre-coating. The high temperature and long residence time in the nip enabled plasticization of the fibers. This led to an irreversible deformation, even after water application. This meant that the smoothness obtained during calendering would be less affected by water-induced roughening during the coating operation.
Journal articles
Magazine articles
Use of kaolin clay in aqueous barrier coating applications, TAPPI Journal November 2023
ABSTRACT: Paper-based packaging with barrier effect, as opposed to single use plastics, is gaining more prominence for sustainability reasons. At the same time, latex- or biopolymer-based aqueous barrier coating dispersions are increasingly being adopted as a better alternative to the traditional barrier coating materials, such as wax, surface active chemicals, and polyethylene. In this work, studies were performed to determine the influence of different kaolin clays in latex binder-based aqueous coatings on barrier properties, namely, oil and grease, water resistance, and water vapor transmission rate, by applying coatings to solid bleached sulfate (SBS) paperboard substrate in the laboratory. The aim was to explore potential benefits of using kaolin clay to replace some of the latex binder in coating and improve or maintain various types of barrier performance and blocking without negatively influencing the other performance attributes, including heat seal. The delaminated clay with the highest shape factor provided improved barrier properties over the clays of low shape factor. The ultrafine and non-delaminated clays required significantly higher coat weights to reach satisfactory barrier properties. Coatings with different latex levels indicated that a considerably high proportion of coarse delaminated clay can be incorporated to replace latex binder, while still achieving exceptional barrier properties. Furthermore, a change in binder system was found to significantly alter the barrier properties and the role that a mineral pigment can play. The results indicate that a proper selection of binder systems for each barrier property would be required while considering the clay/latex coating systems.
Journal articles
Magazine articles
Advanced real-time digital microscopy of foaming processes, TAPPI Journal January 2023
ABSTRACT: The properties of aqueous foams play a major role in foam forming and foam coating. Inline real-time foam measurements provide highly desired opportunities for optimization and control of foaming processes. This paper presents inline digital microscopy measurements of aqueous foams in foaming processes. It presents methods for providing detailed information on foam quality parameters, such as foam density and foam homogeneity in real time from the process. In addition, this study evaluates the performance of transillumination and front-light illumination in imaging of foams. The tests show very good results for the transillumination approach. Limitations of the image-based optical technique are discussed, and the precision of bubble size distribution measurement is assessed with a certificated reference substance. The measured foam densities are compared against the reference foam densities in the range 100•300 g/L, providing a linear correlation with R2 value of 0.99. In the case of heterogenous foams with a wide bubble size distribution, the bubble size-dependent dimensionless depth of field must be taken into account to obtain accurate estimates of foam density. Bubble-scale foam homogeneity is described by the standard deviation of bubble size distribution in foam.
Journal articles
Magazine articles
Predicting strength characteristics of paper in real time using process parameters, TAPPI Journal March 2022
ABSTRACT: Online paper strength testing methods are currently unavailable, and papermakers have to wait for manufacture of a complete reel to assess quality. The current methodology is to test a very small sample of data (less than 0.005%) of the reel to confirm that the paper meets the specifications. This paper attempts to predict paper properties on a running paper machine so that papermakers can see the test values predicted in real time while changing various process parameters. This study was conducted at a recycled containerboard mill in Chicago using the multivariate analysis method. The program provided by Braincube was used to identify all parameters that affect strength characteristics. Nearly 1600 parameters were analyzed using a regression model to identify the major parameters that can help to predict sheet strength characteristics. The coefficients from the regression model were used with real-time data to predict sheet strength characteristics. Comparing the prediction with test results showed good correlation (95% in some cases). The process parameters identified related well to the papermaking process, thereby validating the model. If this method is used, it may be possible to predict various elastic moduli (E11, E12, E22, etc.) in the future as the next step, rather than the traditional single number “strength” tests used in the containerboard industry, such as ring crush test (RCT), corrugating medium test (CMT), and short-span compression strength test.
Journal articles
Magazine articles
Factors affecting the free shrinkage of handsheets: apparent density, fines content, water retention value, and grammage, TAPPI JOURNAL June 2018
Factors affecting the free shrinkage of handsheets: apparent density, fines content, water retention value, and grammage, TAPPI JOURNAL June 2018
Journal articles
Does kraft hardwood and softwood pulp viscosity correlate to
Does kraft hardwood and softwood pulp viscosity correlate to paper properties?, October 2016 TAPPI JOURNAL