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Control of malodorous gases emission from wet-end white water with hydrogen peroxide, TAPPI Journal October 2021
ABSTRACT: White water is highly recycled in the papermaking process so that its quality is easily deteriorated, thus producing lots of malodorous gases that are extremely harmful to human health and the environment. In this paper, the effect of hydrogen peroxide (H2O2) on the control of malodorous gases released from white water was investigated. The results showed that the released amount of total volatile organic compounds (TVOC) decreased gradually with the increase of H2O2 dosage. Specifically, the TVOC emission reached the minimum as the H2O2 dosage was 1.5 mmol/L, and meanwhile, the hydrogen sulfide (H2S) and ammonia (NH3) were almost completely removed. It was also found that pH had little effect on the release of TVOC as H2O2 was added, but it evidently affect-ed the release of H2S and NH3. When the pH value of the white water was changed to 4.0 or 9.0, the emission of TVOC decreased slightly, while both H2S and NH3 were completely removed in both cases. The ferrous ions (Fe2+) and the copper ions (Cu2+) were found to promote the generation of hydroxyl radicals (HO•) out of H2O2, enhancing its inhibition on the release of malodorous gases from white water. The Fe2+/H2O2 system and Cu2+/H2O2 system exhibited similar efficiency in inhibiting the TVOC releasing, whereas the Cu2+/H2O2 system showed better perfor-mance in removing H2S and NH3.
Journal articles
Magazine articles
Lignin-based resins for kraft paper applications, TAPPI Journal November 2019
ABSTRACT: We investigated miscanthus (MS) and willow (W) lignin-furfural based resins as potential reinforce-ment agents on softwood and hardwood kraft paper. These resins might be sustainable alternatives to the commercial phenolformaldehyde (PF) resins. Phenol is a petrochemical product and formaldehyde has been classified as a carcinogen by the U.S. Environmental Protection Agency. The lignin used in this study was derived from hot water extraction (160ºC, 2 h) of MS and W biomass, and may be considered sulfur-free. These biorefinery lignins were characterized for their chemical composition and inherent properties via wet chemistry and instrumental techniques. The resin blends (MS-resin and W-resin) were characterized for their molecular weight, thermal behavior, and mechanical properties. Mechanical properties were measured by the resin’s ability to reinforce softwood and hard-wood kraft papers. The effect of adding hexamethylenetetramine (HMTA), a curing agent, to the resin was also examined. Mixtures of PF and lignin-based resins were investigated to further explore ways to reduce use of non-renewables, phenol, and carcinogenic formaldehyde. The results show that lignin-based resins have the potential to replace PF resins in kraft paper applications. For softwood paper, the highest strength was achieved using W-resin, without HMTA (2.5 times greater than PF with HMTA). For hardwood paper, MS-resin with HMTA gave the highest strength (2.3 times higher than PF with HMTA). The lignin-based resins, without HMTA, also yielded mechanical properties comparable to PF with HMTA.
Magazine articles
Shop talk: reducing voc emissions with thermal oxidation units, TAPPI JOURNAL, December 1997, Vol. 80(12)
Shop talk: reducing voc emissions with thermal oxidation units, TAPPI JOURNAL, December 1997, Vol. 80(12)
Magazine articles
Operations teams run a woodyard, TAPPI JOURNAL, December 1996, Vol. 79(12)
Operations teams run a woodyard, TAPPI JOURNAL, December 1996, Vol. 79(12)
Magazine articles
Local section development efforts earn distinction for paul magnabosco, TAPPI JOURNAL, March 1996, Vol. 79(3)
Local section development efforts earn distinction for paul magnabosco, TAPPI JOURNAL, March 1996, Vol. 79(3)
Magazine articles
1995 pulping conference succees with opportunities to participate, TAPPI JOURNAL, May 1996, Vol. 79(5)
1995 pulping conference succees with opportunities to participate, TAPPI JOURNAL, May 1996, Vol. 79(5)
Magazine articles
China: now and in the future, TAPPI JOURNAL, May 1996, Vol. 79(5)
China: now and in the future, TAPPI JOURNAL, May 1996, Vol. 79(5)
Magazine articles
ISO 9000 registration-avoiding unnecessary procedures, TAPPI JOURNAL, November 1996, Vol. 79(11)
ISO 9000 registration-avoiding unnecessary procedures, TAPPI JOURNAL, November 1996, Vol. 79(11)
Magazine articles
The enemy within, TAPPI JOURNAL, April 1997, Vol. 80(4)
The enemy within, TAPPI JOURNAL, April 1997, Vol. 80(4)
Magazine articles
Anhydrous ammonia storage vessels in the pulp and paper industry, TAPPI JOURNAL, April 1997, Vol. 80(4)
Anhydrous ammonia storage vessels in the pulp and paper industry, TAPPI JOURNAL, April 1997, Vol. 80(4)