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Eucalyptus black liquor properties in a lignin extraction process: density, dry solids, viscosity, inorganic, and organic content, TAPPI Journal March 2023
ABSTRACT: Extracting lignin from black liquor is becoming more common, although only a few research papers discuss the impact of the process on the liquor’s primary properties. This work aims to determine the changes in black liquor properties as it undergoes a lignin extraction process using carbon dioxide (CO2). A diluted eucalyptus black liquor sample (DBL) was acidified with CO2 to a final pH of 8.5. After filtration, the kraft lignin was removed, and the filtrated lignin lean black liquor (LLBL) was collected. Five acidified black liquors (ABL) samples were collected during acidification at pH 10.5; 10.0; 9.5; 9.0; and 8.5. The samples were analyzed regarding lignin content in solution, sodium carbonate (Na2CO3), sodium sulfate (Na2SO4), density, dry solids content, and viscosity. While Na2SO4 remained almost constant, Na2CO3 presented an enormous increase in its concentration when comparing DBL with LLBL. As pH decreased, the lignin content in the solution was also reduced due to lignin precipitation. The results showed similar behavior for dry solids, density, and viscosity of the supernatant, but an increase in density was observed around pH 9.00. In light of this, the density of LLBL turns out to be closer to the one in the initial DBL. The significant increase in carbonate content could explain this behavior during acidification with CO2 once the inorganic content significantly influences the property. The viscosity was determined from 10 s-1 to 2000 s-1. We observed a Newtonian behavior for all samples. The increase in carbonate content in the sample is crucial information to the recovery cycle, especially for calculating the mass and energy balance when targeting the use of the LLBL.
Magazine articles
Views from the top: ceos offer global perspectives on the pulp and paper industries, TAPPI JOURNAL, August 1999, Vol. 82(8)
Views from the top: ceos offer global perspectives on the pulp and paper industries, TAPPI JOURNAL, August 1999, Vol. 82(8)
Magazine articles
1994 polymers, laminations and coatings conference highlights technology basics, TAPPI JOURNAL, December 1994, Vol. 77(12)
1994 polymers, laminations and coatings conference highlights technology basics, TAPPI JOURNAL, December 1994, Vol. 77(12)
Magazine articles
The role of science in setting the environmental agenda, TAPPI JOURNAL, September 2000, Vol. 83(9)
The role of science in setting the environmental agenda, TAPPI JOURNAL, September 2000, Vol. 83(9)
Magazine articles
The r & t system: everyone is responsible for innovation, TAPPI JOURNAL, September 2000, Vol. 83(9)
The r & t system: everyone is responsible for innovation, TAPPI JOURNAL, September 2000, Vol. 83(9)
Magazine articles
A guide to developing a best management practices (bmp) plan for spent liquor, part II, TAPPI JOURNAL, December 1999, Vol. 82(12)
A guide to developing a best management practices (bmp) plan for spent liquor, part II, TAPPI JOURNAL, December 1999, Vol. 82(12)
Magazine articles
Alberta newsprint and alberta research council bring deinking pilot plant on-stream, TAPPI JOURNAL, December 1992, Vol. 75(12)
Alberta newsprint and alberta research council bring deinking pilot plant on-stream, TAPPI JOURNAL, December 1992, Vol. 75(12)
Magazine articles
Operations teams run a woodyard, TAPPI JOURNAL, December 1996, Vol. 79(12)
Operations teams run a woodyard, TAPPI JOURNAL, December 1996, Vol. 79(12)
Magazine articles
Environmental issues continue to be a major industry concern, TAPPI JOURNAL, September 2000, Vol. 83(9)
Environmental issues continue to be a major industry concern, TAPPI JOURNAL, September 2000, Vol. 83(9)
Magazine articles
Taiwan holds first symposium on environmentally friendly and emerging technologies for a sustainable industry, TAPPI JOURNAL, September 2000, Vol. 83(9)
Taiwan holds first symposium on environmentally friendly and emerging technologies for a sustainable industry, TAPPI JOURNAL, September 2000, Vol. 83(9)