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Papermaking properties of bacterial nanocellulose produced from mother of vinegar, a waste product after classical vinegar production, TAPPI Journal April 2020

ABSTRACT: Bacterial nanocellulose (BNC) has gained a lot of attention in recent years due to its nano-size-derived properties. Although it is essentially chemically similar to plant-derived cellulose, it has smaller size and is enriched in free hydroxyl groups, which greatly improve mechanical properties of reinforced paper. However, although BNC has some unique features, it comes at a high price. In this paper, we introduce a new solution for BNC production. We have isolated bacterial nanocellulose directly from agro-industrial waste—mother of vinegar—and used it in the production of paper sheets. We show here that paper sheets made with the addition of only 10% bacterial nanocellulose from mother of vinegar substantially improved basic mechanical as well as printing properties of paper.

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Open Access
Editorial: Nanocellulose: What's next?

Many of the researchers in this field in the late 1990s and early 2000s were challenged in terms of translation research issues due to the limited production capacity of nanocellulosics on a global stage. To address this call, several pilot-plant production plants have been developed and can now deliver NC on multikilo/ton scale as these issues are gradually being resolved.

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Open Access
Guest Editorial: Addressing nanocellulose commercialization needs: R&D collaboration is vital, TAPPI Journal April 2019

This special edition of TAPPI Journal presents demonstrable progress toward the goal of commercial-scale implementation of nanocellulose. Steve Winter of International Paper and I, as co-leads of the Cellulosic Nanomaterials team of the Alliance for Pulp & Paper Technology Innovation (APPTI), see this widespread engagement of the research community in developing innovations as critical to successful commercialization. Congratulations and thanks to TAPPI and to the researchers publishing in this issue and elsewhere.

Journal articles
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Open Access
From biorefineries to bioproducts: conversion of pretreated pulp from biorefining streams to lignocellullose nanofibers, TAPPI Journal April 2019

ABSTRACT: This study investigates the use of pretreatment and enzymatic hydrolysis side streams and conver-sion to lignocellulose nanofibers. We used a steam-exploded and partial enzymatic hydrolyzed hardwood pulp and an organosolv pretreated softwood pulp to prepare lignocellulose nanofibers (LCNF) via microfluidization. The ener-gies applied on fibrillation were estimated to examine the energy consumption levels of LCNF production. The ener-gy consumptions of the fibrillation processes of the hardwood LCNF production and the softwood LCNF production were about 7040-14080 kWh/ton and 4640 kWh/ton on a dry material basis, respectively. The morphology and dimension of developed hardwood and softwood LCNFs and the stability and rheological behavior of their suspen-sions were investigated and are discussed.

Journal articles
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Open Access
The winding mechanics of laminate webs, TAPPI Journal February 2020

ABSTRACT: Models that describe the residual stresses due to winding single-layer webs at the end of roll-to-roll manufacturing machines are mature. These models have been used to reduce or avoid defects that are due to winding. Many laminated products exist where two or more webs have been joined to form a thicker composite web. The properties of the web layers provide a unique functionality to the product being manufactured. No laminate winding models exist in the literature. This paper will focus on the development of a laminate winding model and laboratory test verification of the model.

Journal articles
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Open Access
Controlling porosity and density of nanocellulose aerogels for superhydrophobic light materials, TAPPI JOURNAL March 2018

Controlling porosity and density of nanocellulose aerogels for superhydrophobic light materials, TAPPI JOURNAL March 2018

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Open Access
Degradation of 2,4-dichlorophenol by melamine amine cellulos

Degradation of 2,4-dichlorophenol by melamine amine cellulose- immobilized lacasses, TAPPI JOURNAL October 2017

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Open Access
A new approach for the preparation of cellulose nanocrystals from bamboo pulp through extremely low acid hydrolysis, TAPPI Journal January 2020

ABSTRACT: As a renewable and biodegradable nanomaterial, cellulose nanocrystal (CNC) has a wide range of potential applications, but production of CNC faces significant challenges in capital investment and manufacturing cost. In this work, the one-step preparation of CNC from bleached kraft bamboo pulp by extremely low acid (concen-tration of acid = 0.1 wt%) hydrolysis was demonstrated. The experimental data indicated that the yield of CNC was strongly affected by the operating pressure and concentration of hydrochloric acid (HCl), as well as temperature. Rod-like CNC with a mean particle size of 524 nm was obtained through an extremely low acid (ELA) hydrolysis pro-cess. The yield of CNC can reach to 37.1% by an ELA hydrolysis process at 180°C for 60 min with 0.08 wt% HCl and 20 MPa operating pressure. The Fourier transform-infrared spectroscopy (FTIR) measurements show that the as-pre-pared CNC maintained cellulose structure. Compared with a conventional CNC prepared by strong sulfuric acid (H2SO4) hydrolysis, the CNC prepared by ELA hydrolysis process exhibited much higher thermal stability.

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Open Access
Effects of orders of addition in nanocellulose•cationic starch• colloidal silica systems for papermaking, TAPPI Journal October 2022

ABSTRACT: Two orders of addition were compared when preparing paper handsheets from recycled copy paper furnish in combination with nanofibrillated cellulose (NFC), cationic starch, colloidal silica, and cationic retention aid (cPAM; cationic polyacrylamide). Faster dewatering and higher fine-particle retention were obtained at equal optimized dosages of additives when the colloidal silica was added last, after addition of the cPAM. The same order of addition also provided a higher gain in the paper’s tensile strength. However, higher paper stiffness was achieved when the colloidal silica was instead added to the NFC, after its pretreatment with cationic starch. Results were consistent with the principle that papermaking additives added shortly before sheetforming tend to have the largest effects on drainage and retention. The results also demonstrated a sensitivity to the relative dosages of positively and negatively charged additives.

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Open Access
Extensive function of green synthesized titania nanoparticles: Photodegradation of Congo red, TAPPI Journal September 2023

ABSTRACT: Several extensive research studies have explored the advantages of green templates in the synthesis of structure and morphology-controlled photocatalytic nanomaterials. This paper compares the abilities of zingiber rhizome extract (ZE) and tapioca starch extracts (TS) in modifying the surface and optical properties of titania nanoparticles (TNP) synthesized by solgel technique. The synthesized nanocatalysts were characterized using various physicochemical techniques. While zingiber (ginger) extract effectively promotes the formation of dual anatase and rutile phases, tapioca extract supports formation of the single anatase phase of titania. These two extracts were examined for the degradation of Congo red in the presence of sunlight. The photomineralization and recyclability of catalysts were evaluated through total organic content analysis. The easy recovery and reusability of zingiber and tapioca biomasses, along with good control over the growth of nanoparticles, enable them to be implicit novel green templates in the successful synthesis of photoactive mesoporous nanotitania.