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Next generation dry strength additives: Leveraging on-site synthesis to develop high performance glyoxalated polyacrylamides, TAPPI Journal January 2024
ABSTRACT: Although glyoxalated polyacrylamides (gPAMs) have been described since the 1950s, the freedom to design new materials based on this chemistry has been limited by practical concerns; namely, a balance between solution concentration and material characteristics must be met to make the economics of gPAM strength additives work for the paper industry. For traditional “delivered” gPAMs, only a very narrow range of polyacrylamide molecular weights and compositions could be considered for glyoxalation. However, the development and successful implementation of automated reactor equipment that allows for the synthesis of gPAMs from glyoxal and polyacrylamide copolymers at the mill, known as “on-site” glyoxalation, obviates the shipping and stability concerns that have traditionally held back gPAM development. As such, on-site generators represent a platform that enables the glyoxalation of materials that would otherwise not have been suitable for use in a traditionally delivered gPAM product. These on-site generators therefore open new avenues for polymer design to allow for the creation of the next generation of strength additives. By leveraging the synthetic freedom of the on-site generators, a suite of high performance gPAMs has been designed, yielding materials that provide both exceptional strength and drainage performance in poor quality furnishes.
Journal articles
Magazine articles
Improving monochloramine performance with innovative sensor-controlled dosing, TAPPI Journal January 2024
ABSTRACT: Monochloramine (MCA) has become one of the major oxidant chemistries for biological control in the paper industry. Feedback control, such as oxidative-reductive potential (ORP), is often used to provide better control of a dosing scheme. The trademarked Ackumen MCA-i is a chemical-digital solution that uses artificial intelligence with actionable insights to stabilize the wet-end process, providing improved performance and reduction in overall chemical costs. Accurate sensor-controlled dosing can be tied to multiple inputs, such as production rates, grade changes, pH, ORP, chlorine residual, freshwater usage, and more. In this study, a case history will be presented to demonstrate how this technology provided a more consistent MCA molecule throughout the process, resulting in a higher level of efficacy and reduction in chemical costs.
Journal articles
Applications of tension and nip load profile measurement using a novel roll mounted electret film sensor, TAPPI JOURNAL April 2010
Applications of tension and nip load profile measurement using a novel roll mounted electret film sensor, TAPPI JOURNAL April 2010
Journal articles
Effects of impregnation time on hardwood kraft pulp characteristics and papermaking potential â?¢ a mill study, TAPPI JOURNAL April 2010
Effects of impregnation time on hardwood kraft pulp characteristics and papermaking potential • a mill study, TAPPI JOURNAL April 2010
Journal articles
Starch-modified fillers for linerboard and paper grades: A perspective review, TAPPI JOURNAL April 2010
Starch-modified fillers for linerboard and paper grades: A perspective review, TAPPI JOURNAL April 2010
Journal articles
CFD-Based Modeling of Kraft Char Beds â?¢ Part 2: A Study on the Effects of Droplet Size and Bed Shape on Bed Processes, TAPPI JOURNAL February 2010
CFD-Based Modeling of Kraft Char Beds • Part 2: A Study on the Effects of Droplet Size and Bed Shape on Bed Processes, TAPPI JOURNAL February 2010
Journal articles
Understanding the Role of Surface Active Substances in Flotation Deinking Mills by Coupling Surfactant and Ink Balance With Process Simulation, TAPPI JOURNAL February 2010
Understanding the Role of Surface Active Substances in Flotation Deinking Mills by Coupling Surfactant and Ink Balance With Process Simulation, TAPPI JOURNAL February 2010
Journal articles
Superhydrophobic paper coating containing nonconventional clay, TAPPI JOURNAL November 2010
Superhydrophobic paper coating containing nonconventional clay, TAPPI JOURNAL November 2010
Journal articles
Z-direction fiber orientation in paperboard, TAPPI JOURNAL October 2010
Z-direction fiber orientation in paperboard, TAPPI JOURNAL October 2010
Journal articles
Magazine articles
Dielectric spectroscopic studies of biological material evolution and application to paper, TAPPI JOURNAL September 2018
Dielectric spectroscopic studies of biological material evolution and application to paper, TAPPI JOURNAL September 2018