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Journal articles
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Life cycle carbon analysis of packaging products containing purposely grown nonwood fibers: A case study on the use of switchgrass pulp for linerboard and corrugating medium, TAPPI Journal March 2024

ABSTRACT: Sustainability is driving innovation in the pulp and paper industry to produce goods with lower carbon footprints. Although most of the efforts are currently focused on increasing energy efficiency or switching to renewable fuels, the attention toward alternative feedstocks has increased in recent years. Claims of nonwood fibers requiring lower use of chemicals and energy than wood fibers, along with negative consumer perceptions of tree felling, are helping purposely grown nonwoods to gain market share. The potential nonwood fiber environmental superiority over virgin or recycled wood fibers remains controversial and is often driven more by emotion and public perception rather than facts. This paper estimates the carbon footprint of corrugating medium and linerboard containing switchgrass pulp compared to analogous wood-based materials. The study includes a life cycle carbon analysis spanning from cradle to gate, which comprises stages for fiber production, pulping, papermaking, and corresponding transportation. Carbon footprints for virgin linerboard, recycled linerboard, virgin medium, and recycled medium were estimated at around 510, 620, 460, and 670 kg carbon dioxide equivalent per metric ton (kg CO2eq/t), respectively. Replacing 30% of the virgin or recycled material with switchgrass pulp translated into carbon footprint increases of around 60%, 45%, 62%, and 38%, respectively. Thus, for the proposed case study, the results suggest that switchgrass-based medium and linerboard can present a higher carbon footprint than products made from virgin and recycled wood fibers. The main driver is the production of nonwood mechanical pulp.This study was designed to mitigate part of the uncertainty around the environmental sustainability of medium and linerboard made from the selected purposely grown nonwood fibers.

Journal articles
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Open Access
Effects of varying total titratable alkali and causticizing efficiency targets on kraft pulp mill productivity, TAPPI Journal March 2024

ABSTRACT: The kraft mill causticizing area is often overlooked and undervalued when it comes to mill optimization; however, the operation of the causticizing plant has downstream effects on the entire liquor cycle. Setting the right targets for the causticizing plant can have a tremendous effect on mill operating costs, as well as push the production bottleneck from one unit operation to another. The key performance parameters associated with the causticizing plant itself are liquor total titratable alkali (TTA) and causticizing efficiency. Individual facilities choose their TTA and causticizing efficiency targets based on their goals, the limits of their equipment, and past experiences. This gives a variety of operating strategies in practice, but what are the implications for optimizing total titratable alkali and causticizing efficiency, and what level of optimization can be achieved through implementation of modern technology? This paper reviews the results of several different operational strategies and models the effects of these different approaches on kraft mill liquor cycle.

Journal articles
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Open Access
Factors affecting phosphorus uptake/dissolution during slaking and causticizing, TAPPI Journal March 2024

ABSTRACT: Hydroxide is regenerated in the recovery cycle of kraft pulp mills by the addition of lime (CaO) to green liquor. Phosphate in green liquor can react with the lime during slaking/causticizing. Total titratable alkali (TTA), sulfidity, the concentration of phosphate in the green liquor, temperature, and the liming ratio were all variables explored in this work to determine their influence on phosphorus uptake and dissolution. Experiments were also run in which the lime was slaked before being added to the green liquor to separate reactions with phosphate during slaking and reactions that occur during causticizing. Both reburnt lime and technical grade CaO were used. The experiment results indicate that phosphorus primarily reacts with slaked lime (Ca(OH)2), and that the final concentration of phosphate in the white liquor at the end of slaking and causticizing is nearly independent of the initial concentration of phosphorus and only mildly dependent on the carbonate concentration in the green liquor. There do appear to be differences in the rate at which phosphate reacts with reburnt lime and technical grade CaO, though the reason for this was not determined.

Journal articles
Magazine articles
Open Access
Utilization of Areca leaf residues for sustainable production of greyboard, TAPPI Journal May 2024

ABSTRACT: This study primarily focused on the production of greyboard using waste materials from small scale industries, and specifically using Areca leaf waste fibers as a sustainable and environmentally friendly resource. Areca leaf waste fibers were employed as the primary raw material for greyboard manufacturing. The resulting greyboard exhibited commendable properties, including a tear index of 7.53 mN·m2/g, tensile index of 18.34·N·m/g (i.e., breaking length of 1870 m), burst factor of 9.24 (gf/cm2)/(g/m2) and stiffness factor of 33.1. This greyboard was created through a series of steps, including hydrothermal treatment of the material at 155°C and mechanical pulping refinement. The produced greyboard met the specifications outlined in the Indian Standard 2617 (1967) for greyboard. The key objective of this work was to leverage agricultural waste resources to develop a chemical-free greyboard, resulting in reduced waste disposal in open fields and a decrease in chemical usage within the greyboard manufacturing industry. Various characterization techniques, including field emission scanning electron microscopy (FE-SEM), attenuated total reflection•Fourier transform infrared (ATR-FTIR) analysis, and X-ray diffraction (XRD), were used to assess the fiber quality, including aspects such as functional groups, morphology, and crystallinity for the materials used in the manufacturing process.

Journal articles
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Open Access
Continuous digester process safety improvements • Stress corrosion cracking and overpressure protection lessons learned and opportunities, TAPPI Journal October 2024

ABSTRACT: Georgia-Pacific has recent experience with continuous digester stress corrosion cracking (SCC) repairs where the extent of SCC was more than previous spot inspections had predicted (one digester had anodic protection, one did not). This paper offers case studies of reviewed and improved digester inspections by use of “boat” samples to quantify the depth of cracking mechanism. Boat sample test data is used to support repair recommendations based on hardness testing. Georgia-Pacific also reviewed overpressure protection systems and corrected gaps found in these systems. These included updating to the latest original equipment manufacturer (OEM) designs and formalizing functional testing procedures and practices. This review of digester inspection, testing, and repairs since 2020 provides: (1) a basis for including a 3rd party corrosion expert to be a part of inspections; (2) removes the use of power-wire brushes; (3) enhances digester inspection with 100% phased-array ultrasonic testing to detect SCC; and (4) ensures overpressure protection design and testing is aligned with corporate needs and the site-specific challenges.

Journal articles
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Open Access
How to use total dissolved solids measurements to evaluate the performance of diffuser washers—A mill study, TAPPI Journal April 2020

ABSTRACT: Various types of pulp washing equipment are available. Each washing device has a unique mechanical construction, and the washing principle is often a combination of dilution, thickening, and displacement washing. In this work, the performance of the pressure diffuser washer is studied. In stepwise trials, the effect of the feed and discharge consistencies on the performance of the diffuser was studied. The effect of the downward velocity of the screen on the pressure diffuser’s washing efficiency was also studied. The measurement of total dissolved solids (TDS) by a process refractometer was used as a wash loss measurement unit and the refractometer’s results were used in the calculations of standardized Nordén efficiency (E10) values. The chemical oxygen demand (COD) and conductivity values were also measured and their results compared to the TDS results.The results indicated that feed consistency has a significant effect on the performance and effectiveness of the diffuser washers in the mill. It can also be stated that when the downward velocity of the screen is adjusted to too high a level, the washing efficiency of the pressure diffuser decreases. As a conclusion from the mill tests, it can be stated that even small process parameter changes can provide enhanced diffuser washing at the beginning of the washing line, which has a direct effect on the performance of post-oxygen washing.

Journal articles
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Open Access
Mill experience of calcium carbonate scale formation in green liquor pipelines, TAPPI Journal August 2020

ABSTRACT: Experience of hard calcite (CaCO3) scale formation in green liquor pipelines at four kraft pulp mills was systematically investigated to determine if there is any correlation between the severity of the scaling problem at each mill and the design and operating conditions of its causticizing plant. The results show that the high degree of supersaturation of calcium ions (Ca2+) in the liquor is the main contributing factor. Mills that operate at a lower green liquor total titratable alkali (TTA), higher causticity, and a larger liquor temperature drop are more likely to produce a green liquor that is supersaturated with Ca2+, and thus experience more severe scaling problems. In order to minimize CaCO3 scaling, the green liquor handling equipment should be operated as steady as possible to avoid conditions that allow Ca2+ to be supersaturated. The strategies include minimizing variations in liquor TTA, insulating the green liquor pipelines to reduce temperature gradients, and adding lime mud to weak wash to provide seeds for precipitation to occur on mud particles instead of on metal substrate.

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Open Access
Low-temperature precausticizing — a hopeful approach for green liquor desilication, TAPPI JOURNAL February 2017

Low-temperature precausticizing — a hopeful approach for green liquor desilication, TAPPI JOURNAL February 2017

Journal articles
Magazine articles
Open Access
Removal of silicon from green liquor with low-temperature precausticizing, TAPPI JOURNAL January 2017

Removal of silicon from green liquor with low-temperature precausticizing, TAPPI JOURNAL January 2017

Journal articles
Magazine articles
Open Access
Kinetics of sulfur dioxide-alcohol-water (SAW) pulping of su

Kinetics of sulfur dioxide-alcohol-water (SAW) pulping of sugarcane straw (SCS), TAPPI JOURNAL June 2017