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Journal articles
Open Access
Hydrogen peroxide and caustic soda: Dancing with a dragon while bleaching, TAPPI JOURNAL July 2013

Authors: Peter W. Hart; Carl Houtman; and Kilby Hirth | ABSTRACT: When hydrogen peroxide is mixed with caustic soda, an auto-accelerating reaction can lead to generation of significant amounts of heat and oxygen. On the basis of experiments using typical pulp mill process concentration and temperatures, a relatively simple kinetic model has been developed. Evaluation of these model results reveals that hydrogen peroxide-caustic soda systems are extremely sensitive to hydrogen peroxide:caustic soda ratio, transition metal contamination, and temperature. Small changes in initial conditions can result in a closed system becoming explosive. Analysis of model results was used to develop guidelines for safer application of hydrogen peroxide in a mill setting.

Journal articles
Open Access
Removal of silicon from green liquor with carbon dioxide in the chemical recovery process of wheat straw soda pulping, TAPPI JOURNAL March 2013

Removal of silicon from green liquor with carbon dioxide in the chemical recovery process of wheat straw soda pulping, TAPPI JOURNAL March 2013

Journal articles
Open Access
Effects of flashing on spray characteristics of splashplate nozzles, TAPPI JOURNAL May 2013

Effects of flashing on spray characteristics of splashplate nozzles, TAPPI JOURNAL May 2013

Journal articles
Open Access
Pressure Screen Capacity-Current Findings on the Role of Wire Width and Height, TAPPI JOURNAL, January 2007

Pressure Screen Capacity-Current Findings on the Role of Wire Width and Height, TAPPI JOURNAL, January 2007

Journal articles
Open Access
Filtration properties of lignin precipitated from black liquor, TAPPI JOURNAL, July 2007

Filtration properties of lignin precipitated from black liquor, TAPPI JOURNAL, July 2007

Journal articles
Open Access
Modeling pulp fiber suspension rheology, TAPPI JOURNAL, July 2007

Modeling pulp fiber suspension rheology, TAPPI JOURNAL, July 2007

Journal articles
Open Access
Optimization of the Enzymatic Activation of a Dissolving Pulp Before Viscose Manufacture, TAPPI JOURNAL, June 2007

Optimization of the Enzymatic Activation of a Dissolving Pulp Before Viscose Manufacture, TAPPI JOURNAL, June 2007

Journal articles
Open Access
Impact of Deadload Reduction in the Kraft Chemical Recovery System, TAPPI JOURNAL, June 2007

Impact of Deadload Reduction in the Kraft Chemical Recovery System, TAPPI JOURNAL, June 2007

Journal articles
Open Access
Low Sludge Yield Biofilm Activated Sludge (BAS) Upgrade - Quesnel River Pulp, TAPPI JOURNAL, May 2007

Low Sludge Yield Biofilm Activated Sludge (BAS) Upgrade - Quesnel River Pulp, TAPPI JOURNAL, May 2007

Journal articles
Open Access
Synergistic effects between chemical mechanical pulps and chemical pulps from hardwoods, TAPPI JOURNAL November 2007

Synergistic effects between chemical mechanical pulps and chemical pulps from hardwoods, TAPPI JOURNAL November 2007