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Journal articles
Open Access
Effect of pulp refining on thixotropy of cellulose fiber suspensions, TAPPI Journal September 2025

ABSTRACT: This paper presents results on the thixotropic behavior of low-consistency bleached eucalyptus fiber suspensions that had been mechanically treated. The pulps were refined in a PFI mill at different numbers of revolutions (0, 3000, and 6000) to study the effect of refining intensity on the viscosity time-response of fiber suspensions. In steady rheological tests, all the suspensions exhibited shear thinning behavior and no significant differences were observed after mechanical treatment. Stepwise experiments showed that viscosity continuously increased with time when shear rate was suddenly reduced. Additionally, a delay in time evolution of viscosity was observed as the pulp was more refined. A stretched exponential model was fitted to the experimental results of viscosity.

Journal articles
Open Access
Toward environmental resilience in pulp and paper manufacturing: Water consumption and carbon dioxide emission reductions, TAPPI Journal September 2025

ABSTRACT: Pulp and paper manufacturing is a water- and energy-intensive industrial sector, necessitating improvement of its operational efficiency, as well as reduction of emissions to the maximum extent possible. This review focuses on the reduction of water consumption and carbon dioxide (CO2) emissions that originate in the pulp and paper industry (PPI). First, process simulation and optimization techniques used for water consumption reduction are reviewed. Then, techno-economic analyses of solvent-based CO2 capture from PPI are discussed. Additionally, key actions are proposed for enhancing water consumption reduction and CO2 capture in PPI.

Journal articles
Magazine articles
Open Access
Influence of tensile straining and fibril angle on the stiffness and strength of previously dried kraft pulp fibers, TAPPI JOURNAL July 2018

Influence of tensile straining and fibril angle on the stiffness and strength of previously dried kraft pulp fibers, TAPPI JOURNAL July 2018

Journal articles
Magazine articles
Open Access
A hundred years of corrosion in the pulp and paper industry, TAPPI JOURNAL May 2018

A hundred years of corrosion in the pulp and paper industry, TAPPI JOURNAL May 2018

Journal articles
Magazine articles
Open Access
Editorial: 2018 TAPPI Journal features diverse content, TAPPI Journal November 2018

Editorial: 2018 TAPPI Journal features diverse content, TAPPI Journal November 2018

Journal articles
Magazine articles
Open Access
Understanding the risks and rewards of using 50% vs. 10% strength peroxide in pulp bleach plants, TAPPI Journal November 2018

Authors: Alan W. Rudie and Peter W. Hart | ABSTRACT: The use of 50% concentration and 10% concentration hydrogen peroxide were evaluated for chemical and mechanical pulp bleach plants at storage and at point of use. Several dangerous occurrences have been documented when the supply of 50% peroxide going into the pulping process was not stopped during a process failure. Startup conditions and leaking block valves during maintenance outages have also contributed to explosions. Although hazardous events have occurred, 50% peroxide can be stored safely with proper precautions and engineering controls. For point of use in a chemical bleach plant, it is recommended to dilute the peroxide to 10% prior to application, because risk does not outweigh the benefit. For point of use in a mechanical bleach plant, it is recommended to use 50% peroxide going into a bleach liquor mixing system that includes the other chemicals used to maintain the brightening reaction rate. When 50% peroxide is used, it is critical that proper engineering controls are used to mitigate any risks.

Journal articles
Magazine articles
Open Access
Using multistage models to evaluate how pulp washing after the first extraction stage impacts elemental chlorine-free bleach demand, TAPPI Journal November 2018

Using multistage models to evaluate how pulp washing after the first extraction stage impacts elemental chlorine-free bleach demand, TAPPI Journal November 2018

Journal articles
Magazine articles
Open Access
Laboratory method for determining the source of brightness loss at a southern United States bleached paperboard mill, TAPPI Journal October 2018

Laboratory method for determining the source of brightness loss at a southern United States bleached paperboard mill, TAPPI Journal October 2018

Journal articles
Magazine articles
Open Access
Kraft pulp bleaching with a P-stage catalyzed by both bicarbonate and TAED, TAPPI Journal July 2019

ABSTRACT: Peroxide bleaching of softwood and hardwood (eucalypt) kraft pulps was performed in solutions of sodium bicarbonate (NaHCO3), sodium carbonate (Na2CO3), and sodium hydroxide (NaOH). The conventional P stage (hydrogen peroxide + sodium hydroxide; H2O2 + NaOH) was the most effective brightening system without an additional activator. However, peroxide activation by bicarbonate anion (HCO3•) was obvious in all cases where NaHCO3 or Na2CO3 was used. When N,N,N’,N’-tetraacetylethylenediamine (TAED) was added to the bleaching sys-tem, Na2CO3 as the alkali source afforded equal or slightly higher bleached brightness compared to NaOH usage for both the softwood and hardwood pulps. This outcome is attributed to simultaneous peroxide activation by HCO3• and TAED. When applied to the eucalypt pulp, the H2O2/Na2CO3/TAED bleaching system also decreased the bright-ness loss due to thermal reversion.

Journal articles
Magazine articles
Open Access
Fundamental molecular characterization and comparison of the O, D0, and E stage effluents from hardwood pulp bleaching, TAPPI Journal 2019

ABSTRACT: The present study characterized effluents from the O, D0, and E stages using nuclear magnetic reso-nance (NMR) and gel permeation chromatography (GPC) techniques to better understand the chemical nature of the dissolved organics formed from the bleaching of a high-yield hardwood kraft pulp. Understanding the structures and molecular weight distribution of these organics is the first step in developing methods to mitigate these contam-inates in the discharged effluents. The results indicated that the molecular weight distribution (MWD) of the dis-solved organics from oxygen delignification effluent is broader than those from D0 and E stage effluents. In addition, the O stage filtrate contained considerable amounts of lignin and xylan fragments, which showed its efficiency in removing such materials. The effluent from the D0 stage contained a lower amount of high molecular weight frag-ments and a higher amount of low molecular weight fragments versus the O-stage filtrate. Aromatic structures were nearly absent in the D0 stage filtrate, but the degraded organic material, presumably from oxidized lignin, contained olefinic (C=C) and carbonyl (C=O) functional groups. Furthermore, higher molecular weight fragments were detected in the E-stage effluent, presumably due to the extensive solubilization and removal of the oxidized lignin generated from the D0 pulp.