Search
Use the search bar or filters below to find any TAPPI product or publication.
Filters
Content Type
Publications
Level of Knowledge
Committees
Collections
Journal articles
Magazine articles
Lignin-based resins for kraft paper applications, TAPPI Journal November 2019
ABSTRACT: We investigated miscanthus (MS) and willow (W) lignin-furfural based resins as potential reinforce-ment agents on softwood and hardwood kraft paper. These resins might be sustainable alternatives to the commercial phenolformaldehyde (PF) resins. Phenol is a petrochemical product and formaldehyde has been classified as a carcinogen by the U.S. Environmental Protection Agency. The lignin used in this study was derived from hot water extraction (160ºC, 2 h) of MS and W biomass, and may be considered sulfur-free. These biorefinery lignins were characterized for their chemical composition and inherent properties via wet chemistry and instrumental techniques. The resin blends (MS-resin and W-resin) were characterized for their molecular weight, thermal behavior, and mechanical properties. Mechanical properties were measured by the resin’s ability to reinforce softwood and hard-wood kraft papers. The effect of adding hexamethylenetetramine (HMTA), a curing agent, to the resin was also examined. Mixtures of PF and lignin-based resins were investigated to further explore ways to reduce use of non-renewables, phenol, and carcinogenic formaldehyde. The results show that lignin-based resins have the potential to replace PF resins in kraft paper applications. For softwood paper, the highest strength was achieved using W-resin, without HMTA (2.5 times greater than PF with HMTA). For hardwood paper, MS-resin with HMTA gave the highest strength (2.3 times higher than PF with HMTA). The lignin-based resins, without HMTA, also yielded mechanical properties comparable to PF with HMTA.
Magazine articles
Using climate change policies for u.s. pulp and paper industry efficiency, TAPPI JOURNAL, July 2000, Vol. 83(7)
Using climate change policies for u.s. pulp and paper industry efficiency, TAPPI JOURNAL, July 2000, Vol. 83(7)
Magazine articles
Industry leaders: jukka harmala leads stora enso into new global age, TAPPI JOURNAL, May 2000, Vol. 83(5)
Industry leaders: jukka harmala leads stora enso into new global age, TAPPI JOURNAL, May 2000, Vol. 83(5)
Magazine articles
A personal mount st. helens experience, TAPPI JOURNAL, May 2000, Vol. 83(5)
A personal mount st. helens experience, TAPPI JOURNAL, May 2000, Vol. 83(5)
Journal articles
NCASI technical studies of environmental issues affecting fiber supplies, TAPPI JOURNAL, November 2000, Vol. 83(11)
NCASI technical studies of environmental issues affecting fiber supplies, TAPPI JOURNAL, November 2000, Vol. 83(11)
Magazine articles
Energy: recovering capital and cutting costs, TAPPI JOURNAL, November 2000, Vol. 83(11)
Energy: recovering capital and cutting costs, TAPPI JOURNAL, November 2000, Vol. 83(11)
Journal articles
Hesperaloe funifera - an excellent reinforcement fiber for mechanical paper grades, TAPPI JOURNAL, November 2000, Vol. 83(11)
Hesperaloe funifera - an excellent reinforcement fiber for mechanical paper grades, TAPPI JOURNAL, November 2000, Vol. 83(11)
Journal articles
Differentiated permeability surface layer (dpsl) pressing theory, TAPPI JOURNAL, November 2000, Vol. 83(11)
Differentiated permeability surface layer (dpsl) pressing theory, TAPPI JOURNAL, November 2000, Vol. 83(11)
Journal articles
Infrared analysis for process control in the pulp and paper industry, TAPPI JOURNAL, October 2000, Vol. 83(10)
Infrared analysis for process control in the pulp and paper industry, TAPPI JOURNAL, October 2000, Vol. 83(10)
Magazine articles
What's new with tappi test methods?, TAPPI JOURNAL, September 2000, Vol. 83(9)
What's new with tappi test methods?, TAPPI JOURNAL, September 2000, Vol. 83(9)