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Lignin-based resins for kraft paper applications, TAPPI Journal November 2019
ABSTRACT: We investigated miscanthus (MS) and willow (W) lignin-furfural based resins as potential reinforce-ment agents on softwood and hardwood kraft paper. These resins might be sustainable alternatives to the commercial phenolformaldehyde (PF) resins. Phenol is a petrochemical product and formaldehyde has been classified as a carcinogen by the U.S. Environmental Protection Agency. The lignin used in this study was derived from hot water extraction (160ºC, 2 h) of MS and W biomass, and may be considered sulfur-free. These biorefinery lignins were characterized for their chemical composition and inherent properties via wet chemistry and instrumental techniques. The resin blends (MS-resin and W-resin) were characterized for their molecular weight, thermal behavior, and mechanical properties. Mechanical properties were measured by the resin’s ability to reinforce softwood and hard-wood kraft papers. The effect of adding hexamethylenetetramine (HMTA), a curing agent, to the resin was also examined. Mixtures of PF and lignin-based resins were investigated to further explore ways to reduce use of non-renewables, phenol, and carcinogenic formaldehyde. The results show that lignin-based resins have the potential to replace PF resins in kraft paper applications. For softwood paper, the highest strength was achieved using W-resin, without HMTA (2.5 times greater than PF with HMTA). For hardwood paper, MS-resin with HMTA gave the highest strength (2.3 times higher than PF with HMTA). The lignin-based resins, without HMTA, also yielded mechanical properties comparable to PF with HMTA.
Journal articles
CFD-Based Modeling of Kraft Char Beds â?¢ Part 1: Char Bed Burning Model, TAPPI JOURNAL February 2010
CFD-Based Modeling of Kraft Char Beds • Part 1: Char Bed Burning Model, TAPPI JOURNAL February 2010
Journal articles
Influence of oxidation and cationization on the properties of thermomechanical pulp fibers, TAPPI JOURNAL October 2010
Influence of oxidation and cationization on the properties of thermomechanical pulp fibers, TAPPI JOURNAL October 2010
Journal articles
Characterization of spruce thermomechanical pulps at the fiber cell wall level: a method for quantitatively assessing pulp fiber development using Simonsâ?? stain, TAPPI JOURNAL October 2010
Characterization of spruce thermomechanical pulps at the fiber cell wall level: a method for quantitatively assessing pulp fiber development using Simons’ stain, TAPPI JOURNAL October 2010
Journal articles
Comparative annual cost efficiency between thermal and chemical oxidation of TRS in kraft mills, TAPPI JOURNAL, July 2005, Vol. 4(7) (200 KB)
Comparative annual cost efficiency between thermal and chemical oxidation of TRS in kraft mills, TAPPI JOURNAL, July 2005, Vol. 4(7) (200 KB)
Journal articles
Use of enzymes for reduction in refining energy - laboratory
Use of enzymes for reduction in refining energy - laboratory studies, TAPPI JOURNAL, November 2006
Journal articles
Image analytical monitoring of paper quality - a feasibility
Image analytical monitoring of paper quality - a feasibility study, TAPPI JOURNAL, November 2006
Journal articles
Editor's Notes: Ready for a Test Drive, TAPPI JOURNAL, Novem
Editor's Notes: Ready for a Test Drive, TAPPI JOURNAL, November, 2006
Journal articles
Editor's Notes: Ready for a Test Drive, TAPPI JOURNAL, Novem
Editor's Notes: Ready for a Test Drive, TAPPI JOURNAL, November, 2006
Journal articles
Magazine articles
Editoral: Investing in the future: Writing and peer-reviewing for TAPPI Journal, TAPPI Journal July 2024
ABSTRACT: Those who actively participate in TAPPI realize how much there is to gain from the networking, educational resources, career development, and other opportunities that come with this involvement. One important opportunity is the ability to share your work and expertise with others in your field, and an excellent way to do this is by taking part in the TAPPI Journal peer-review process, either as an author or a reviewer or both.