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Rheological characteristics of platy kaolin, TAPPI JOURNAL September 2019

ABSTRACT: Platy kaolin can provide significant value in the coating of paper and paperboard. It can be used in multiple applications and can provide benefits such as titanium dioxide (TiO2) extension, smoothness improvement, improved print gloss or ink set rates, calendering intensity reduction, and improved barrier properties. It is not a pigment that can be simply substituted for traditional hydrous kaolin without some adjustment to the coating formulation. These adjustments can be as simple as reducing solids, but may require binder changes as well. The coater setup may need to be adjusted because of the unique rheological behaviors these pigments exhibit.The unique rheological characteristics of platy kaolin are explored here. Measurements of the water retention of platy kaolin containing coatings confirm that water retention is not reduced in comparison to more blocky kaolin pigments, despite the lower coating solids at which they need to be run. This means that the rheological characteristics are the most important in understanding the runnability. An extensive analysis reveals some unique behaviors that need to be understood when utilizing these materials. Viscoelastic measurements indicate that, for this binder system, Tan d is mainly a function of solids. This may explain how weeping is initiated on a blade coater. The degree of shear thinning behaviors is investigated using the Ostwald de-Waele power law. The immobilization point was determined using the Dougherty-Krieger equation and related to the work of Weeks at the University of Maine on blade coater runnability. An indirect measure of particle shape and size synergy is also demonstrated using the Dougherty-Krieger equation parameters.

Journal articles
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Open Access
Flow characteristics of drag-reducing natural bamboo fiber suspensions with minimal environmental load, TAPPI Journal September 2019

ABSTRACT: The reduction of pipe friction loss by adding drag-reducing agents has attracted attention as an aid to energy conservation. Drag-reducing agents induce drag reduction (DR) effects and should have a minimal environmental load, with natural resource-saving potential. This study demonstrates bamboo fiber as a drag-reducing agent that saves natural resources and has a low environmental load. Using pressure drop measurements, we report DR with suspensions of bamboo fibers with the average diameter of 13.3 µm and aspect ratio of 98.7. The maximum DR obtained in this experiment is 43% at the concentration of 4000 ppm and pipe diameter of 30 mm; DR is affected by the Reynolds number, suspension concentration, and pipe diameter. In addition, the bamboo fibers can be easily removed from the suspensions by filtration. We found that low-environmental-load bamboo fiber has DR effects like those of other fibers; its effects are greater than those of conventional synthetic fibers and wood pulp. Furthermore, it is resistant to mechanical degradation, recoverable, and recyclable. Therefore, DR effects can be selectively obtained by adding the fibers only when DR is needed; the fibers can then be collected when DR is no longer necessary. This method might greatly expand the application range of DR agents. The results demonstrate the usefulness of bamboo fibers as DR additives.

Journal articles
Magazine articles
Open Access
Static and dynamic sorption of lignin removed Populus euramericana, TAPPI JOURNAL February 2018

Static and dynamic sorption of lignin removed Populus euramericana, TAPPI JOURNAL February 2018

Journal articles
Magazine articles
Open Access
Lignocellulose fibers elaborating super-swollen three-dimensional cellulose hydrogels from solution in N, N-dimethylacetamide/lithium chloride, TAPPI JOURNAL February 2018

Lignocellulose fibers elaborating super-swollen three-dimensional cellulose hydrogels from solution in N, N-dimethylacetamide/lithium chloride, TAPPI JOURNAL February 2018

Journal articles
Magazine articles
Open Access
Functionalization of wood/plant-based natural celluslose fibers with nanomaterials: a review, TAPPI JOURNAL February 2018

Functionalization of wood/plant-based natural celluslose fibers with nanomaterials: a review, TAPPI JOURNAL February 2018

Journal articles
Magazine articles
Open Access
Editorial: The changing face of the coated paper industry, TAPPI JOURNAL January 2018

Editorial: The changing face of the coated paper industry, TAPPI JOURNAL January 2018

Journal articles
Magazine articles
Open Access
Contrasting underlying mechanisms of different barrier coating types, TAPPI Journal January 2018

Contrasting underlying mechanisms of different barrier coating types, TAPPI Journal January 2018

Journal articles
Magazine articles
Open Access
Print quality of flexographic printed paperboard related to coating composition and structure, TAPPI Journal January 2018

Print quality of flexographic printed paperboard related to coating composition and structure, TAPPI Journal January 2018

Journal articles
Magazine articles
Open Access
Editorial: Remembering Phil Clark: A Coating “Master Man”, TAPPI JOURNAL July 2018

Editorial: Remembering Phil Clark: A Coating “Master Man”, TAPPI JOURNAL July 2018

Journal articles
Magazine articles
Open Access
Effects of lignin chemistry on oxygen delignification performance, TAPPI JOURNAL July 2018

Effects of lignin chemistry on oxygen delignification performance, TAPPI JOURNAL July 2018