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Multifunctional barrier coating systems created by multilayer curtain coating, TAPPI Journal November 2023
ABSTRACT: Functional coatings are applied to paper and paperboard substrates to provide resistance, or a barrier, against media such as oil and grease, water, water vapor, and oxygen, for applications such as food packaging, food service, and other non-food packaging. Today, there is increasing interest in developing recyclable and more sustainable approaches for producing these types of packages. This paper focuses on water-based barrier coatings (WBBC) for oil and grease resistance (OGR), water, moisture vapor transmission rate (MVTR), and oxygen barrier performance. The main goal is to create coated systems that can achieve more than one barrier property using multilayer curtain coating (MLCC) in a single application step. One advantage is in optimizing coating material cost with the use of functional chemistry in confined layers where performance is balanced within the coating layered structure. This allows simultaneous application of layers of different polymer types in one step to achieve the appropriate performance needs for a given barrier application. This paper provides working examples of using MLCC to create coating structures with multiple barrier properties in a single application pass. Barrier polymers studied include styrene butadiene, styrene acrylate, starch-containing emulsions, and polyvinyl alcohol. The paper also shows the effect of increasing the pigment volume concentration with platy clay or fine ground calcium carbonate on MVTR and OGR barrier properties.
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Surface energy considerations for offset printing of coated paper and paperboard, TAPPI Journal November 2023
ABSTRACT: Offset printing of coated paper involves the complex interactions of ink with a surface that is characterized by three major properties: roughness, porosity, and related pore network structure and surface chemistry (related to surface free energy [SFE]). The effects of porosity and roughness are relatively well understood and are documented in the literature, whereas the influence of surface chemistry is much less studied and therefore the focus of this paper. The key results shown include: i) Coating porosity has a negligible effect on SFE determination by contact angle using two fluids. ii) The chemistry of the latex polymer in the coating formulation dominates the influence on SFE compared to pigment, with any surface energy differences present in the pigment being almost completely masked by latex. iii) Wetting agent and corona treatment can impact water absorption rate and surface spreading of water, resulting in small differences in printability. Increasing the concentration of the surfactant on a coated surface indicates switching orientation of the surfactant molecules, giving a “step wise” printing result. When looking to improve offset printability by selection of different pigments, the variation in SFE is less important than variation in either surface roughness or porosity.
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Rice straw-based sustainable food packaging material with improved strength and barrier properties: Development and characterization, TAPPI Journal October 2023
ABSTRACT: Sustainable food packaging paper with high barrier and strength properties was developed with rice straw nanocellulose materials. Pulping and bleaching of rice straw were performed using an organosolv pulping and DED (D: chlorine dioxide bleaching; E: sodium hydroxide extraction) bleaching sequence. Bleached rice straw pulp was refined to 90°SR using a laboratory Valley beater. The laboratory handsheets were prepared using pulp slurry at 40°SR and 90°SR. The handsheets of cellulose nanofibrils (CNFs) made of highly refined pulp (90°SR) were surface sized using alkyl ketene dimer (AKD) wax to increase the barrier properties of paper for selective food packaging applications. The paper samples were tested for mechanical, optical, surface, and barrier properties, including tensile index, burst index, tearing index, bending stiffness, elongation, porosity, apparent density, opacity, Cobb value, water vapor transmission rate (WVTR), oil and grease resistance, and contact angle. The refined pulp (90°SR) was analyzed using field-emission scanning electron microscopy (FE-SEM), and it was observed that the morphology of the developed fibers changes to the nanoscale (<100 nm) for at least one dimension. The particle size distribution of the refined pulp using DLS analyzer also confirmed the cellulose fibers to near nanoscale. It was concluded that nanofibers were formed by a high degree of the mechanical pulp refining process and found to be much more economical than alternative processes in this direction. The sample handsheets of CNFs showed good strength and barrier properties. The barrier properties further increased when surface sizing was done using low-cost, nontoxic, and biodegradable AKD wax.
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Using bleaching stage models for benchmarking hardwood ECF bleach plants, TAPPI Journal October 2023
ABSTRACT: Steady-state models estimated the performance of the D0(EOP)D1 bleach sequence at two mixed hardwood bleach plants in the southern United States. At Mill 1, the full sequence’s chlorine dioxide charge that brightens the pulp to ~84% ISO was monitored for two weeks. Mill 2 considered the partial sequence that brightens the pulp to ~86% ISO for nearly four weeks. Elevated levels of chlorine dioxide were linked to increased washer carryover in brownstock and extraction areas. For Mills 1 and 2, an extra 0.24% and 0.33% chlorine dioxide was consumed in the D0 stage. This extra bleach demand was equivalent to an additional 4.8 and 5.5 kappa load to the brownstock, respectively. Some differences were observed for the D1 stage. Mill 1 had extraction carryover that averaged 1.1 units higher than was measured, contributing to use of an extra 0.22% of chlorine dioxide. Mill 2 had extraction carryover that averaged between 0 and 0.7 kappa units and consumed up to 0.13% more chlorine dioxide. Another data set from Mill 2 showed high brownstock and extraction carryover, leading to ~0.90% more total chlorine dioxide usage to brighten to 84% ISO. Overall, this investigation illustrated that the models could be employed as benchmarks.
Journal articles
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Perfluoroalkyl and polyfluoroalkyl substances (PFAS) — Fibrous substrates, TAPPI Journal September 2023
ABSTRACT: Perfluoroalkyl and polyfluoroalkyl substances (PFAS) have been implemented during the finishing process of textiles such as upholstery, clothing, personal protective equipment, and sports gear to provide water resistance. Currently, PFAS are still present at quantifiable levels in consumer products and food, even though many companies have started to phase out PFAS treatment with non-toxic water repellant replacements given the possible detrimental health effects suggested by current research. This paper is a detailed review that focuses on how PFAS are implemented in textile production and sources of PFAS contamination during chemical treatments. This review also addresses current legislation on PFAS emissions and trade regulations to decrease exposure of consumers due to toxicokinetics and mechanisms of action through-out the body that are still not well understood. This paper includes a literature review on possible PFAS related health conditions shown from past research and contains suggested toxicity levels, exposure routes, duration, and pathways detailed to the best of our ability.
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Cross-flow separation characteristics and piloting of graphene oxide nanofiltration membrane sheets and tubes for kraft black liquor concentration, TAPPI Journal September 2023
ABSTRACT: Dewatering of weak black liquor (WBL) in the kraft cycle by evaporation is highly energy intensive. Membranes are an attractive alternative for energy-efficient dewatering, but existing commercial polymeric or ceramic membranes are either degraded in BL or have high capital costs. Our recent works have demonstrated the engineering of graphene oxide (GO) nanofiltration membranes, their stability and promising performance in BL conditions, and preliminary scale-up into sheets and tubes. Here, we describe in detail the separation characteristics of GO membrane sheets and tubes under real BL conditions and crossflow operation. Recycle-mode piloting of a GO tubular membrane showed average “production flux” of 16 L/m2/h (LMH) and high rejections of lignin (98.3%), total solids (66%), and total organic carbon (83%), with no signs of irreversible fouling identified. A corresponding GO sheet membrane produced an average flux of ~25 LMH and maintained high lignin rejection of ~97% during a slipstream pilot at a kraft mill site using WBL with ~16 wt% total solids (TS). Finally, we piloted a Dow/DuPont XUS1808 polyamide composite reverse osmosis (RO) membrane for last-mile processing of the GO nanofiltration membrane permeate. The RO membrane showed a steady state flux of 19 LMH at 65 bar and produced ~0.02 wt% TS water product, which is highly suitable for reuse in pulp washing operations in the kraft process. The results have strong positive implications for the industrial application of GO membranes in BL concentration and other related applications.
Journal articles
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Extensive function of green synthesized titania nanoparticles: Photodegradation of Congo red, TAPPI Journal September 2023
ABSTRACT: Several extensive research studies have explored the advantages of green templates in the synthesis of structure and morphology-controlled photocatalytic nanomaterials. This paper compares the abilities of zingiber rhizome extract (ZE) and tapioca starch extracts (TS) in modifying the surface and optical properties of titania nanoparticles (TNP) synthesized by solgel technique. The synthesized nanocatalysts were characterized using various physicochemical techniques. While zingiber (ginger) extract effectively promotes the formation of dual anatase and rutile phases, tapioca extract supports formation of the single anatase phase of titania. These two extracts were examined for the degradation of Congo red in the presence of sunlight. The photomineralization and recyclability of catalysts were evaluated through total organic content analysis. The easy recovery and reusability of zingiber and tapioca biomasses, along with good control over the growth of nanoparticles, enable them to be implicit novel green templates in the successful synthesis of photoactive mesoporous nanotitania.
Journal articles
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Boiler retrofit improves efficiency and increases biomass firing rates, TAPPI Journal March 2021
ABSTRACT: Domtar’s fluff pulp mill in Plymouth, NC, USA, operates two biomass/hog fuel fired boilers (HFBs). For energy consolidation and reliability improvement, Domtar wanted to decommission the No. 1 HFB and refurbish/retrofit the No. 2 HFB. The No. 2 HFB was designed to burn pulverized coal and/or biomass on a traveling grate. The steaming capacity was 500,000 lb/h from coal and 400,000 lb/h from biomass. However, it had never sustained this design biomass steaming rate. As the sole power boiler, the No. 2 HFB would need to sustain 400,000 lb/h of biomass steam during peak loads. An extensive evaluation by a combustion and boiler technologies supplier was undertaken. The evaluation involved field testing, analysis, and computational fluid dynamics (CFD) modeling, and it identified several bottle-necks and deficiencies to achieving the No. 2 HFB’s biomass steam goal. These bottlenecks included an inadequate combustion system; insufficient heat capture; excessive combustion air temperature; inadequate sweetwater con-denser (SWC) capacity; and limited induced draft fan capacity.To address the identified deficiencies, various upgrades were engineered and implemented. These upgrades included modern pneumatic fuel distributors; a modern sidewall, interlaced overfire air (OFA) system; a new, larger economizer; modified feedwater piping to increase SWC capacity; replacement of the scrubber with a dry electrostatic precipitator; and upgraded boiler controls.With the deployment of these upgrades, the No. 2 HFB achieved the targeted biomass steaming rate of 400,000 lb/h, along with lowered stack gas and combustion air temperatures. All mandated emissions limit tests at 500,000 lb/h of steam with 400,000 lb/h of biomass steam were passed, and Domtar reports a 10% reduction in fuel firing rates, which represents significant fuel savings. In addition, the mill was able to decommission the No. 1 HFB, which has substantially lowered operating and maintenance costs.
Journal articles
Magazine articles
Peracetate/singlet oxygen chemistry used in post-bleaching of kraft pulp as a practical oxidant for paper machines, TAPPI Journal May 2021
ABSTRACT: The use of a novel sodium peracetate/singlet oxygen chemistry for brightening bleached kraft pulp shows exciting potential for technical performance, supply logistics, safety, and cost reduction. Potential chemical carryover to the paper machine raises questions about whether peracetate will impact paper machine performance, such as metal corrosion, useful press felt life, and interference with existing biocide programs or paper machine chemistry. Sodium peracetate/singlet oxygen chemistry can be used in high-density storage chests for brightening/whitening and to increase color stability. Any oxidant used directly before the paper machine has the possibility of impacting paper machine operations. Traditional oxidants used in bleaching, such as chlorine dioxide and hydrogen peroxide, are known to cause corrosion on machinery metals and press felts. Hydrogen peroxide residuals can interfere with common biocide programs. Traditional oxidants used in biocide treatments themselves significantly degrade press felt life when the rule-of-thumb concentration thresholds are exceeded. Sodium peracetate is evaluated in this paper for its impact on nylon press felt fiber degradation, metal corrosion, and interference with typical biocide programs.Laboratory results indicate that sodium peracetate/singlet oxygen chemistry is less corrosive than chlorine, bromine, and hydrogen peroxide on press felt nylon fiber and can therefore be used at higher levels than those chemistries to increase brightness without increasing negative downstream impact. Sodium peracetate can also be used with current biocide programs without negative impacts such as consumptive degradation. Higher residuals of peracetate going to the paper machine may be useful as a biocide itself and can complement existing programs, allowing those programs to stay within their safe operating levels and thereby extend press felt useful life.
Journal articles
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Gas dispersion in the oxygen delignification process, TAPPI Journal May 2021
ABSTRACT: There has been very little knowledge about the state of gas dispersion in the oxygen delignification process, even though this has a major impact on the performance of the reactor. This paper presents a new continu-ous inline method for measuring oxygen bubble size distribution in the reactor, as well as results from studies con-ducted in softwood and hardwood lines. This new measurement worked well, and new information about oxygen bubble size, as well as how different reactor conditions affected the distribution, was obtained. For example:œ In the softwood line, the mean volume-weighted bubble size was about 0.1 mm, whereas in the hardwood line, this size was almost 10 times higher. For both lines, there was considerable variation in the measured bubble size over the long term.œ For both lines, an increase in mixer rotation speed caused a discernible decrease in the bubble size, and an increase in oxygen charge caused a discernible increase in the bubble size.œ In the softwood line, no coalescence of the bubbles in the reactor was observed, but in the hardwood line, some coalescence of the larger bubbles occurred.œ In the test conducted in the hardwood line, the use of brownstock washer defoamer caused a discernible increase in oxygen bubble size.œ In the hardwood line, reactor pressure had a noticeable effect on the amount of delignification, which indicated that improving mass transfer of oxygen (e.g., by decreasing the oxygen bubble size, in this case) should also have an increasing effect on the delignification.