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Critical parameters for tall oil separation I: The importance of ration of fatty acids to rosin acids, TAPPI Journal September 2019
ABSTRACT: Tall oil is a valuable byproduct in chemical pulping of wood, and its fractions have a large spectrum of applications as chemical precursors, detergents, and fuel. High recovery of tall oil is important for the economic and environmental profile of chemical pulp mills. The purpose of this study was to investigate critical parameters of tall oil separation from black liquor. To investigate this in a controlled way, we developed a model test system using a “synthetic” black liquor (active cooking chemicals OH- and HS- ions), a complete process for soap skimming, and determination of recovered tall oil based on solvent extraction and colorimetric analysis, with good reproducibility. We used the developed system to study the effect of the ratio of fatty acids to rosin acids on tall oil separation. When high amounts of rosin acids were present, tall oil recovery was low, while high content of fatty acids above 60% significantly promoted tall oil separation. Therefore, manipulating the content of fatty acids in black liquor before the soap skimming step can significantly affect the tall oil solubility, and hence its separation. The findings open up chemical ways to improve the tall oil yield.
Journal articles
Acid-insoluble and acid-soluble lignin characteristics in kraft pulping of hybrid salix clones, TAPPI JOURNAL August 1988
Acid-insoluble and acid-soluble lignin characteristics in kraft pulping of hybrid salix clones, TAPPI JOURNAL August 1988
Journal articles
Nonwood fiber: Number 2, and trying harder-An interview with Dr. Joseph E. Atchison, TAPPI JOURNAL August 1988
Nonwood fiber: Number 2, and trying harder-An interview with Dr. Joseph E. Atchison, TAPPI JOURNAL August 1988
Journal articles
A wet-laid process for the preparation of random fiber-reinforced composites, TAPPI JOURNAL August 1988
A wet-laid process for the preparation of random fiber-reinforced composites, TAPPI JOURNAL August 1988
Journal articles
A fast-track approach through the design and permit phases for an ash landfill, TAPPI JOURNAL August 1988
A fast-track approach through the design and permit phases for an ash landfill, TAPPI JOURNAL August 1988
Journal articles
Significance of PM10 regulations for the forest products industry, TAPPI JOURNAL August 1988
Significance of PM10 regulations for the forst products industry, TAPPI JOURNAL August 1988
Journal articles
Fibers properties and tearing resistance, TAPPI JOURNAL February 1988 88FEB103
Fibers properties and tearing resistance, TAPPI JOURNAL February 1988
Journal articles
Meltblown polyester solves a food processing filtration problem, TAPPI JOURNAL February 1988 88FEB79
Meltblown polyester solves a food processing filtration problem, TAPPI JOURNAL February 1988
Journal articles
The influence of headbox flow conditions on paper properties and their constancy, TAPPI JOURNAL February 1988 88FEB93
The influence of headbox flow conditions on paper properties and their constancy, TAPPI JOURNAL February 1988
Journal articles
High-solids black liquor combustion-Tampella's Super Combustion system, TAPPI JOURNAL January 1988 88JAN107
High-solids black liquor combustion-Tampella's Super Combustion system, TAPPI JOURNAL January 1988