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A new approach for the preparation of cellulose nanocrystals from bamboo pulp through extremely low acid hydrolysis, TAPPI Journal January 2020

ABSTRACT: As a renewable and biodegradable nanomaterial, cellulose nanocrystal (CNC) has a wide range of potential applications, but production of CNC faces significant challenges in capital investment and manufacturing cost. In this work, the one-step preparation of CNC from bleached kraft bamboo pulp by extremely low acid (concen-tration of acid = 0.1 wt%) hydrolysis was demonstrated. The experimental data indicated that the yield of CNC was strongly affected by the operating pressure and concentration of hydrochloric acid (HCl), as well as temperature. Rod-like CNC with a mean particle size of 524 nm was obtained through an extremely low acid (ELA) hydrolysis pro-cess. The yield of CNC can reach to 37.1% by an ELA hydrolysis process at 180°C for 60 min with 0.08 wt% HCl and 20 MPa operating pressure. The Fourier transform-infrared spectroscopy (FTIR) measurements show that the as-pre-pared CNC maintained cellulose structure. Compared with a conventional CNC prepared by strong sulfuric acid (H2SO4) hydrolysis, the CNC prepared by ELA hydrolysis process exhibited much higher thermal stability.

Journal articles
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Open Access
Root cause analysis of cationic polymer additive efficiency decline in virgin and recycle containerboard mills, TAPPI Journal January 2020

ABSTRACT: It is well known that retention, drainage and strength polymers struggle to perform (if at all) in virgin containerboard mills. In-depth studies have been undertaken in this area for more than seven years, investigating the issue from all directions. A key finding of this work is that soluble lignin is detrimental to chemical efficiency. A strong correlation exists between decreased chemical efficiency and high soluble lignin. Both recycled systems and virgin systems have been studied, and this correlation holds true regardless of furnish. The primary area of concern is virgin container-board, because these mills tend to have the highest lignin levels. Some highly closed recycled mills can also build elevated lignin levels that can negatively affect chemical efficiency.

Journal articles
Magazine articles
Open Access
Guest Editorial: From rocket science to innovation in bioenergy & bioproducts, TAPPI JOURNAL February 2017

Guest Editorial: From rocket science to innovation in bioenergy & bioproducts, TAPPI JOURNAL February 2017

Journal articles
Magazine articles
Open Access
Low-temperature precausticizing — a hopeful approach for green liquor desilication, TAPPI JOURNAL February 2017

Low-temperature precausticizing — a hopeful approach for green liquor desilication, TAPPI JOURNAL February 2017

Journal articles
Magazine articles
Open Access
Removal of silicon from green liquor with low-temperature precausticizing, TAPPI JOURNAL January 2017

Removal of silicon from green liquor with low-temperature precausticizing, TAPPI JOURNAL January 2017

Journal articles
Magazine articles
Open Access
Cellulosic ethanol byproducts as a bulking agent, TAPPI JOURNAL January 2017

Cellulosic ethanol byproducts as a bulking agent, TAPPI JOURNAL January 2017

Journal articles
Magazine articles
Open Access
Editorial: The Laboratory of Soft Materials & Green Chemistr

Editorial: The Laboratory of Soft Materials & Green Chemistry at North Carolina State University, TAPPI JOURNAL July 2017

Journal articles
Magazine articles
Open Access
Reduction of alkali loss in an ash leaching system, TAPPI J

Reduction of alkali loss in an ash leaching system, TAPPI JOURNAL July 2017

Journal articles
Magazine articles
Open Access
Evaluation of the particle size of organosolv lignin in the

Evaluation of the particle size of organosolv lignin in the synthesis of resol resins for plywood and their performance on fire spreading, TAPPI JOURNAL July 2017

Journal articles
Magazine articles
Open Access
Low consistency refining of mechanical pulp — system design

Low consistency refining of mechanical pulp — system design, TAPPI JOURNAL July 2017