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Editor's Note: Great expectations, TAPPI JOURNAL January 201
Editor's Note: Great expectations, TAPPI JOURNAL January 2011
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Magazine articles
The influence of strain rate and pulp properties on the stre
The influence of strain rate and pulp properties on the stress-strain curve and relaxation rate of wet paper, TAPPI JOURNAL August 2015
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Editorial: Art Ragauskas: Eyes on the future, TAPPI JOURNAL
Editorial: Art Ragauskas: Eyes on the future, TAPPI JOURNAL October 2012
Journal articles
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Pilot scale black liquor concentration using pressure driven membrane separation, TAPPI Journal April 2023
ABSTRACT: Black liquor concentration using pressure driven membrane separation has long been proposed as a means of achieving energy savings and breaking production bottlenecks. To date, limitations in membrane performance and stability under black liquor process conditions have prevented those promises from being realized out-side of tightly controlled laboratory settings. In this work, we describe the first successful pilot scale field deployments of a membrane system for black liquor concentration. Using a purpose-built system and commercial sized, spiral wound graphene oxide membrane elements, we have logged nearly 6000 h of runtime across deployments to multiple mill sites. We demonstrate concentration of black liquor from 14% to >20% total solids, while generating permeate water comparable in quality to that of evaporator condensate and an 81% reduction in energy consumption relative to evaporation. At a commercial scale, these results translate to $2 M/year in net energy savings for a typical mill, as well as an opportunity to support production increases or mill expansions. These results represent a significant leap forward in the ability of membrane systems to deliver substantial value via black liquor concentration.
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Evaluation of soap recovery efficiency from black liquor — analytical tools, TAPPI Journal April 2023
ABSTRACT: Soap skimmings (“soap”) are typically recovered from black liquor in kraft mills that process a high percentage of softwood. In many mills, the recovery of soap is inefficient, negatively impacting performance of evaporators and recovery boilers and resulting in loss of potential revenue. A thorough evaluation of soap recovery performance in a kraft mill requires measurement of soap content in black liquor at various sampling locations, especially around the soap skimmer.The standard laboratory method for evaluating soap content in black liquor is a complex, multi-step process that relies on solvent extraction and titration; most mills send these samples to an outside laboratory for this analysis. In this study, 100 black liquor samples, with a wide range of soap concentrations, were tested by the standard solvent extraction method. After additional dilution, each sample was also tested for surface tension with a bubble pressure tensiometer. The results were found to correlate very closely with the solvent extraction tests results. This alternate method, using surface tension measurements of diluted black liquor samples, produces rapid results and can be easily implemented in most kraft mills, which would facilitate much more frequent in-house evaluations of soap recovery performance.
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Integrated study of flue gas flow and superheating process in a recovery boiler using computational fluid dynamics and 1D-process modeling, TAPPI Journal June 2020
ABSTRACT: Superheaters are the last heat exchangers on the steam side in recovery boilers. They are typically made of expensive materials due to the high steam temperature and risks associated with ash-induced corrosion. Therefore, detailed knowledge about the steam properties and material temperature distribution is essential for improving the energy efficiency, cost efficiency, and safety of recovery boilers. In this work, for the first time, a comprehensive one-dimensional (1D) process model (1D-PM) for a superheated steam cycle is developed and linked with a full-scale three-dimensional (3D) computational fluid dynamics (CFD) model of the superheater region flue gas flow. The results indicate that: (1) the geometries of headers and superheater platens affect platen-wise steam mass flow rate distribution (3%•7%); and (2) the CFD solution of the 3D flue gas flow field and platen heat flux distribution coupled with the 1D-PM affect the platen-wise steam superheating temperature (45%•122%) and material temperature distribution (1%•6%). Moreover, it is also found that the commonly-used uniform heat flux distribution approach for the superheating process is not accurate, as it does not consider the effect of flue gas flow field in the superheater region. These new observations clearly demonstrate the value of the present integrated CFD/1D-PM modeling approach.
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Rewet suppression through press felt engineering, TAPPI Journal June 2022
ABSTRACT: Due to the immense energy and associated financial cost of drying paper, achieving a drier web entering the dryers is a key objective in paper manufacture. One major research thrust has been finding a way to increase press solids by mitigating or eliminating rewet in the press section. For decades, solutions to this problem have remained elusive. In this work, we develop a novel approach that significantly reduces rewet by rupturing the liquid channels between felt and web. We illustrate the effects that altering the mechanical and surface properties of the press felt matrix have on the stability of these liquid channels. In a laboratory-scale platen press, a 40% reduction in the residual water of 120 g/m2 southern bleached softwood kraft (SBSK) pulp handsheets after pressing was observed, corresponding to an increase in press solids from 48% to 61%. For reference, pressing under identical conditions with paper blotters, in which minimal rewet is presumed to occur, resulted in 64% solids. Furthermore, we observed enhanced dewatering across a range of basis weights, applied pressures, and felt types. In addition to measuring the solids content of pressed sheets, we capture and analyze video evidence of the mechanisms at play in our improved dewatering technology.
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The Influence of the Fine Structure of Cellulose on the Action of Cellulases, TAPPI Journal June 2022
ABSTRACT: In the hydrolysis of cellulose with enzymes of Aspergillus niger at 47°C., it shown that a great decrease in the rate occurred in the late stage of the reaction, usually with considerable cellulose still reamaining undissolved.
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Web lateral instability caused by nonuniform paper properties, TAPPI Journal January 2022
ABSTRACT: Lateral or cross-machine direction (CD) web movement in printing or converting can cause problems such as misregistration, wrinkles, breaks, and folder issues. The role of paper properties in this problem was studied by measuring lateral web positions on commercial printing presses and on a pilot-scale roll testing facility (RTF). The findings clearly showed that CD profiles of machine direction (MD) tension were a key factor in web stability. Uneven tension profiles cause the web to move towards the low-tension side. Although extremely nonuniform tension profiles are visible as bagginess, more often, tension profiles must be detected by precision devices such as the RTF. Once detected, the profiles may be analyzed to determine the cause of web offset and weaving problems.Causes of tension profiles can originate from nonuniform paper properties. For example, by means of case studies, we show that an uneven moisture profile entering the dryer section can lead to a nonuniform tension profile and lateral web movement. Time-varying changes in basis weight or stiffness may also lead to oscillations in the web’s lateral position. These problems were corrected by identifying the root cause and making appropriate changes. In addition, we developed a mathematical model of lateral stability that explains the underlying mechanisms and can be used to understand and correct causes of lateral web instability.