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Perfluoroalkyl and polyfluoroalkyl substances (PFAS) — Fibrous substrates, TAPPI Journal September 2023
ABSTRACT: Perfluoroalkyl and polyfluoroalkyl substances (PFAS) have been implemented during the finishing process of textiles such as upholstery, clothing, personal protective equipment, and sports gear to provide water resistance. Currently, PFAS are still present at quantifiable levels in consumer products and food, even though many companies have started to phase out PFAS treatment with non-toxic water repellant replacements given the possible detrimental health effects suggested by current research. This paper is a detailed review that focuses on how PFAS are implemented in textile production and sources of PFAS contamination during chemical treatments. This review also addresses current legislation on PFAS emissions and trade regulations to decrease exposure of consumers due to toxicokinetics and mechanisms of action through-out the body that are still not well understood. This paper includes a literature review on possible PFAS related health conditions shown from past research and contains suggested toxicity levels, exposure routes, duration, and pathways detailed to the best of our ability.
Journal articles
Magazine articles
Cross-flow separation characteristics and piloting of graphene oxide nanofiltration membrane sheets and tubes for kraft black liquor concentration, TAPPI Journal September 2023
ABSTRACT: Dewatering of weak black liquor (WBL) in the kraft cycle by evaporation is highly energy intensive. Membranes are an attractive alternative for energy-efficient dewatering, but existing commercial polymeric or ceramic membranes are either degraded in BL or have high capital costs. Our recent works have demonstrated the engineering of graphene oxide (GO) nanofiltration membranes, their stability and promising performance in BL conditions, and preliminary scale-up into sheets and tubes. Here, we describe in detail the separation characteristics of GO membrane sheets and tubes under real BL conditions and crossflow operation. Recycle-mode piloting of a GO tubular membrane showed average “production flux” of 16 L/m2/h (LMH) and high rejections of lignin (98.3%), total solids (66%), and total organic carbon (83%), with no signs of irreversible fouling identified. A corresponding GO sheet membrane produced an average flux of ~25 LMH and maintained high lignin rejection of ~97% during a slipstream pilot at a kraft mill site using WBL with ~16 wt% total solids (TS). Finally, we piloted a Dow/DuPont XUS1808 polyamide composite reverse osmosis (RO) membrane for last-mile processing of the GO nanofiltration membrane permeate. The RO membrane showed a steady state flux of 19 LMH at 65 bar and produced ~0.02 wt% TS water product, which is highly suitable for reuse in pulp washing operations in the kraft process. The results have strong positive implications for the industrial application of GO membranes in BL concentration and other related applications.
Journal articles
Magazine articles
Importance of specimen preparation for edgewise compressive strength (ECT) testing, TAPPI JOURNAL April 2018
Importance of specimen preparation for edgewise compressive strength (ECT) testing, TAPPI JOURNAL April 2018
Journal articles
Magazine articles
Editorial: Douglas Coffin: Paper Physics Guru, TAPPI JOURNAL August 2018
Editorial: Douglas Coffin: Paper Physics Guru, TAPPI JOURNAL August 2018
Journal articles
Magazine articles
Prediction of box failure from paper data for asymmetric corrugated board, TAPPI JOURNAL August 2018
Prediction of box failure from paper data for asymmetric corrugated board, TAPPI JOURNAL August 2018
Journal articles
Magazine articles
Impact of fiber structure on edge-wicking of highly-sized paperboard, TAPPI JOURNAL August 2018
Impact of fiber structure on edge-wicking of highly-sized paperboard, TAPPI JOURNAL August 2018
Magazine articles
F. keith hall earns honors for distinguished service, TAPPI
F. keith hall earns honors for distinguished service, TAPPI JOURNAL, March 1999, Vol. 82(3)
Magazine articles
Martin sees people as key to fraser's success, TAPPI JOURNAL
Martin sees people as key to fraser's success, TAPPI JOURNAL, May 1999, Vol. 82(5)
Magazine articles
Driving for the top at port hawkesbury, TAPPI JOURNAL, May 1
Driving for the top at port hawkesbury, TAPPI JOURNAL, May 1999, Vol. 82(5)
Magazine articles
TAPPI JOURNAL November 1999; Vol. 82; No. 11 - 1999 Coating
TAPPI JOURNAL November 1999; Vol. 82; No. 11 - 1999 Coating and Graphic Arts Conference, TAPPI JOURNAL, November 1999, Vol. 82(11)