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Water chemistry challenges in pulping and papermaking • fundamentals and practical insights: Part 1: Water chemistry fundamentals and pH, TAPPI Journal June 2022
ABSTRACT: Water is an essential component of the papermaking process. Nevertheless, papermakers often overlook its importance compared to fibers and chemical additives. A better understanding of water properties and chemical interactions associated with water at the wet end leads to a sound foundation for high-quality paper production and smooth operation. Not all fresh water and process water is the same. Fresh water varies from mill to mill, primarily due to the location and availability of water sources. Some industrial trends, such as enhancing water conservation and production yield, gradually shift process water quality over time. The current work serves as a primer on water and water chemistry fundamentals to help the papermaker prepare for the future challenges of increased contamination of process water associated with reduced fresh water usage. This paper focuses on basic water chemistry definitions and discusses the impact of pH on wet-end operation. It is clear that pH is a fundamental factor that directly affects the process and impacts other factors relevant to the papermaking process. It is crucial to understand what pH represents, how it is measured, how to select the proper pH and carefully control it, and how to closely maintain the process at target setpoints. Understanding the sensitivity of operation to pH change will lead to an appropriate focus on these issues. In addition to basic theory, we also review onsite experience and practical mill cases. It is imperative to stress that, although critical, pH is not the only chemical parameter impacting papermaking operations. Other factors, such as ionic concentration measured by conductivity, surface, soluble charge, and hardness, are critical and will be discussed in Part II of this series. As pH is a primary and independent factor that impacts various forms of charge and conductivity, the authors decided to start the current series of papers by discussing pH.
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Rewet suppression through press felt engineering, TAPPI Journal June 2022
ABSTRACT: Due to the immense energy and associated financial cost of drying paper, achieving a drier web entering the dryers is a key objective in paper manufacture. One major research thrust has been finding a way to increase press solids by mitigating or eliminating rewet in the press section. For decades, solutions to this problem have remained elusive. In this work, we develop a novel approach that significantly reduces rewet by rupturing the liquid channels between felt and web. We illustrate the effects that altering the mechanical and surface properties of the press felt matrix have on the stability of these liquid channels. In a laboratory-scale platen press, a 40% reduction in the residual water of 120 g/m2 southern bleached softwood kraft (SBSK) pulp handsheets after pressing was observed, corresponding to an increase in press solids from 48% to 61%. For reference, pressing under identical conditions with paper blotters, in which minimal rewet is presumed to occur, resulted in 64% solids. Furthermore, we observed enhanced dewatering across a range of basis weights, applied pressures, and felt types. In addition to measuring the solids content of pressed sheets, we capture and analyze video evidence of the mechanisms at play in our improved dewatering technology.
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The Influence of the Fine Structure of Cellulose on the Action of Cellulases, TAPPI Journal June 2022
ABSTRACT: In the hydrolysis of cellulose with enzymes of Aspergillus niger at 47°C., it shown that a great decrease in the rate occurred in the late stage of the reaction, usually with considerable cellulose still reamaining undissolved.
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Editorial: Reflections on the Page equation, laboratory work, and new concepts, TAPPI Journal May 2022
ABSTRACT: I began teaching paper physics to undergraduates in the late 1980s when the recognized giants in the field were still actively debating their subjects in the literature and scientific conferences.
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Improving refining efficiency with deflocculation, TAPPI Journal May 2022
ABSTRACT: The ability to load a refiner requires the formation of a fiber mat between opposing refiner bars. One of the consequences of this is the formation of flocs that persist through the refiner grooves and exit the refiner. These flocs interfere with sheet strength, requiring additional energy to make up the strength deficit. In addition, flocs can initiate string formation, resulting in machine efficiency issues such as cross-machine profile deterioration and the downtime required to correct it. Novel refiner plate modifications have been shown to improve refining efficiency in otherwise identical refiner plates. Energy savings are typically around 15% of gross refining energy on the basis of the treated stock, although much higher reductions have also been seen. Addressing this previously underappreciated flaw in conventional refining enables greenhouse gas reduction and other benefits related to sheet strength and machine efficiency.
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Web instability in the open draw and the impact on paper machine efficiency, TAPPI Journal May 2022
ABSTRACT: Paper is most likely to break in the first open draw on a paper machine where it is unsupported, wettest, and weakest. Tension is applied to peel the web from the roll surface, as well as minimize web flutter in the open draw. The average tension is well below the breaking point and is often set by adjusting the speed difference between the press and the next machine element by visually observing the behavior of the web. However, machine direction variations caused by instabilities in the paper machine can cause tension swings that exceed the strength of the web. Measurement of the web’s release point from press rolls on pilot and commercial paper machines was used to identify the cause of tension instabilities. Variations in the speed of the paper machine drives and the work of adhesion from the press roll surface were identified as key factors. Fluctuations of paper moisture, which affects the elastic modulus and strength of the web, appear to be less important.
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Editorial: TAPPI Journal 2019 Best Research Paper runner-up focuses on persistent issue of cracking at the fold in coated papers, TAPPI Journal May 2020
ABSTRACT: TAPPI and the TAPPI Journal (TJ) Editorial Board would like congratulate the authors of the runner-up paper to the 2019 TAPPI Journal Best Research Paper Award: Seyyed Mohammad Hashemi Dajan, Douglas W. Bousfield, and Mehdi Tajvidi. Their paper: "Cracking at the fold in double layer coated paper the influence of latex and starch composition," appeared on p. 93 of the February 2019 issue. This coating research was recognized by the TJ Editorial Board for its innovation, creativity, scientific merit, and clear expression of ideas.
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Alternative “green” lime kiln fuels: Part I—Pulping/recovery byproducts, TAPPI Journal May 2020
ABSTRACT: This paper is the first of a two-part series on “green” lime kiln fuels. The first part of this work reviews the use of pulp mill and recovery byproducts as either full or partial replacement of oil or natural gas in the kiln. The second part reviews the use of various forms of woody biomass, bio-oils, gasification, and hydrogen as potential carbon neutral or carbon-free lime kiln fuels.
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Editorial: Steve Ottone: New coating expert for TJ, TAPPI JO
Editorial: Steve Ottone: New coating expert for TJ, TAPPI JOURNAL April 2013
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Guest Editorial: Terry Bliss: Editorial board member "extrem
Guest Editorial: Terry Bliss: Editorial board member "extreme", TAPPI JOURNAL May 2012