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Economic and competitive potential of lignin-based thermoplastics using a multicriteria decision-making method, TAPPI Journal September 2022
ABSTRACT: As a result of new lignin extraction plants hatching and increasing volumes of technical lignin becoming available, a variety of lignin derivatives, including phenolic resins and polyurethane (PU) foams, are reaching the marketplace or being used as intermediate products in many industrial applications. In the spectrum of possible lignin derivatives, thermoplastics appear particularly attractive due to a symbiosis of market, policy, and technology drivers. To assess the preferredness for lignin-based thermoplastics, this paper adapted a risk-oriented methodology formerly applied to assess lignin usage in various applications (phenol-formaldehyde [PF] resins, PU foams, and carbon fiber applications) to the case of lignin-based thermoplastics using hydroxypropylated lignin (HPL) and miscible blends of lignin and polyethylene oxide (PEO). The HPL is considered for garbage bags and agricultural films applications, while lignin-PEO blends are used as replacement for acrylonitrile butadiene styrene (ABS) in applications such as automotive parts. In the methodology, two phased-implementation strategies were defined for each thermoplastic derivative, considering perspectives for profit maximization (90 metric tons/day integrated units) and revenue growth (350 metric tons/day overall capacity), which were considered for implementation within a softwood kraft pulping mill. A set of six criteria representative of the main economic and market competitiveness issues were employed, and their respective importance weights were obtained in a multicriteria decision-making (MCDM) panel.Early-stage techno-economic estimates were done as a basis for the calculation of decision criteria. Compared to product derivatives previously assessed, capital investment for thermoplastic strategies appeared marginally higher due to the required lignin modification steps (on average 30% higher at similar capacity, and 6% for higher-scale revenue diversification strategies). Higher operating costs were also observed due to increased chemical expenses for all thermoplastic strategies, which are ultimately balanced by revenues associated with targeted thermoplastic products, leading to greater annual margins and cash flow generation over the project lifetime for thermoplastic strategies compared to other product applications (58% to 66% higher on average, at similar scale). Benefits of improved economics were reflected in economic criteria, internal rate of return (IRR), and cash flow on capital employed (CFCE), as well as in the price competitiveness criterion, CPC. Overall, the combination of relatively high lignin content in the plastic formulation and the less costly modification method contributed to lignin-PEO strategies, gaining the top two rankings. Based on their overall scores, both strategies defined for HPL would also integrate the group of “preferred” strategies, but are outranked by strategies that consider lignin positioning on PU foam applications.
Journal articles
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Root cause analysis of cationic polymer additive efficiency decline in virgin and recycle containerboard mills, TAPPI Journal January 2020
ABSTRACT: It is well known that retention, drainage and strength polymers struggle to perform (if at all) in virgin containerboard mills. In-depth studies have been undertaken in this area for more than seven years, investigating the issue from all directions. A key finding of this work is that soluble lignin is detrimental to chemical efficiency. A strong correlation exists between decreased chemical efficiency and high soluble lignin. Both recycled systems and virgin systems have been studied, and this correlation holds true regardless of furnish. The primary area of concern is virgin container-board, because these mills tend to have the highest lignin levels. Some highly closed recycled mills can also build elevated lignin levels that can negatively affect chemical efficiency.
Journal articles
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Multifunctional barrier coating systems created by multilayer curtain coating, TAPPI Journal November 2020
ABSTRACT: Functional coatings are applied to paper and paperboard substrates to provide resistance, or a barrier, against media such as oil and grease (OGR), water, water vapor as measured by moisture vapor transmission rate (MVTR), and oxygen, for applications such as food packaging, food service, and other non-food packaging. Typical functional barrier coatings can be created by applying a solid coating or extruded film, a solvent based-coating, or a water-based coating to the paper substrate using various means of coating applicators.This paper focuses on water-based barrier coatings (WBBC) for OGR, water, MVTR, and oxygen barriers. The main goal was to create coated systems that can achieve more than one barrier property using multilayer curtain coating (MLCC). Curtain coating has emerged as the premier low-impact application me thod for coated paper and paperboard. This paper provides examples using MLCC to create coating structures that provide multiple barrier properties in a single coating step. Barrier polymer systems studied include styrene butadiene, styrene acrylate, vinyl acrylic, and natural materials, as well as proprietary additives where required to give desired performance. The paper also shows how the specific coating layers can be optimized to produce the desired property profile, without concern for blocking, as the addition of a non-blocking top layer can be applied in the MLCC structure as well. Experiments on base sheet types also shows the importance of applying the multilayer structure on a pre-coated surface in order to improve coating thickness consistency and potentially allow for the reduction of more expensive layer components.
Journal articles
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Numerical analysis of slot die coating of nanocellulosic materials, TAPPI Journal November 2020
ABSTRACT: Nanocellulosic coatings as a food packaging material are of commercial interest due to their nontoxic nature, renewability, and excellent barrier properties. Complex shear-thinning rheology poses challenges in designing and sizing equipment to pump, mix, and process the suspension and actual coating process. This study aims to determine the effectiveness of computational fluid dynamics (CFD) in predicting nanocellulosic suspension flow in light of existing rheological data. We employ and compare three distinct rheological models to characterize the rheology and flow of nanocellulose suspensions through a slot die coater, where the model parame-ters are established from existing slot rheometry measurements. A volume-of-fluid (VoF) based finite volume meth-od is employed to simulate the flow in a slot die operated in an unconventional metering mode. Results with the Casson model predict the presence of unyielded regions in the flow, which was not captured using the power law model. These stagnation regions will incur coatability issues stemming from flow intermittencies and lead to poten-tial defects in the coating layer, including fracture. The results suggest that a rheological model that includes yield stress should be considered while modeling such flows. A need for better rheological data to model nanocellulosic flows, especially at high consistencies and shear rates, is also highlighted.
Journal articles
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The use of hollow sphere pigments as strength additives in paper and paperboard coatings—Part 1: The predictive nature of packing models on coating properties, TAPPI Journal November 2020
ABSTRACT: Hollow sphere pigments (HSPs) are widely used at low levels in coated paper to increase coating bulk and to provide gloss to the final sheet. However, HSPs also provide an ideal system through which one can examine the effect of pigment size and particle packing within a coating due to their unimodal and tunable particle sizes. The work presented in Part 1 and Part 2 of this study will discuss the use of blends of traditional inorganic pigments and HSPs in coating formulations across a variety of applications for improved coating strength. Part 1 of this study focuses on the theory of bimodal spherical packing and demonstrates the predictive nature of packing models on the properties of coating systems containing HSPs of two different sizes. This study also examines conditions where the model fails by examining the effect of particle size on coating strength in sytems like thermal paper basecoats where the non-HSP component has a broad particle size distribution, and how these surprising trends can be used to generate better-than-expected thermal printing performance in systems with low HSP/clay ratios. Part 2 of this study focuses on the incorporation of HSPs of different particle sizes into paperboard formulations to affect coating strength and opacity.
Journal articles
Magazine articles
Z-directional testing of paperboard in combined tensile and compression loading, TAPPI Journal May 2024
ABSTRACT: The out-of-plane properties of paperboard are important in several converting applications such as printing, sealing, creasing, and calendering. A juxtaposed tensile and compression curve in the z direction (ZD) will, however, appear to have a kink or discontinuity at 0 stress. The purpose of the present work is to capture the continuous transition between tension and compression and to increase the understanding of the complex ZD properties of paperboard by cyclic testing. In this attempt to unify the ZD tensile and compressive behavior of paperboard, samples were laminated to the testing platens using heat seal laminate film. The method for adhering the samples was compared to samples that were laminated and glued to the testing platens. The edge effects of the cutting method were evaluated in compression testing with samples not attached to the testing platens. The flat slope seen in the initial part of the pure compression curve disappeared when the samples were laminated to the testing platens. The flat slope was instead replaced by a continuous response in the transition across 0 N. The stiffness in the transition region resembled the response in tensile testing. When the testing is cycled, the material exhibits a history dependence. Starting the cycle in either compression or tensile will show an effect on the stiffness at the transition, as well as the compressive stiffness. However, the ultimate tensile strength is unaffected.
Journal articles
Magazine articles
Orifice geometry as a tool for evaluating extensional flow resistance of barrier coating colors, TAPPI Journal November 2024
ABSTRACT: Knowledge of extensional flow behavior of coating colors can be beneficial for improving runnability and eliminating defects in various coating processes. The current work evaluates the use of an orifice geometry attached to a commercial capillary viscometer as a tool to obtain extensional flow properties of barrier coating dispersions. By measuring the pressure drop across the orifice as a function of flow velocity, the method presents the flow resistance as Euler number at industrially relevant high deformation rates. The results agree with the earlier results obtained with a capillary entrance pressure loss technique. The type of polymer additive is shown to control the extensional flow resistance, with high molecular weight linear flexible polymers such as polyethylene oxide (PEO) and polyvinyl alcohol (PVOH) having highest impact. The orifice method offers advantages over other approaches, including the need for only a small sample amount, ease of measurement, and access to high deformation rates.
Magazine articles
Editor's Note: Bright future for coating at ACFS, TAPPI JOUR
Editor's Note: Bright future for coating at ACFS, TAPPI JOURNAL November 2010
Magazine articles
What does it take to get my paper published?, TAPPI JOURNAL,
What does it take to get my paper published?, TAPPI JOURNAL, March 2002, Vol. 1(1) (62KB)
Journal articles
Magazine articles
The Shendye-Fleming OBA Index for paper and paperboard, TAPPI Journal March 2022
ABSTRACT: We are proposing a new one-dimensional scale to calculate the effects of optical brightening agents (OBA) on the bluish appearance of paper. This index is separate from brightness and whiteness indices.In the paper industry, one-dimensional scales are widely used for determining optical properties of paper and paperboard. Whiteness, tint, brightness, yellowness, and opacity are the most common optical properties of paper and paperboard. Most of the papers have a blue cast generated by addition of OBA or blue dyes. This blue cast is given because of the human perception that bluer is whiter, up to a certain limit. To quantify this effect, it is necessary to determine how much blue cast paper and paperboard have. As the printing industry follows the ISO 3664 Standard for viewing, which has a D50 light source, this also plays a very important role in showing a blue cast. Color perception is based on light source and light reflected from an object. The ultraviolet (UV) component in D50 interacts with OBA to provide a reflection in the blue region of the visible spectrum. Use of a UV blocking filter results in measurements without the effect of emission in the blue region. This difference is used in determining the OBA effect in the visible range of the paper. This equation is known as the Shendye-Fleming OBA Index.