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Journal articles
Open Access
The hyperbolic theory of light scattering, tensile strength, and density in paper, TAPPI JOURNAL November 2011

The hyperbolic theory of light scattering, tensile strength, and density in paper, TAPPI JOURNAL November 2011

Journal articles
Open Access
Cavitation-jet deinking: A new technology for deinking of recovered paper, TAPPI JOURNAL September 2014

Cavitation-jet deinking: A new technology for deinking of recovered paper, TAPPI JOURNAL September 2014

Journal articles
Open Access
Offset ink tack and rheology correlation part 2: determining in real time the solids content of ink-on-paper using the ink tack force-time integral, TAPPI JOURNAL, Online Exclusive, July 2003, Vol. 2(7) (267KB)

Offset ink tack and rheology correlation part 2: determining in real time the solids content of ink-on-paper using the ink tack force-time integral, TAPPI JOURNAL, Online Exclusive, July 2003, Vol. 2(7) (267KB)

Journal articles
Open Access
Facile preparation of nanofiller-paper using mixed office paper without deinking, TAPPI JOURNAL 2015 March - 15MAR167

Facile preparation of nanofiller-paper using mixed office paper without deinking, TAPPI JOURNAL March 2015

Journal articles
Open Access
89JUN163

The influence of chlorine ratio and oxygen bleaching on the formation of PCDFs and PCDDs in pulp bleaching - Part 2: a full mill study, TAPPI JOURNAL June 1989

Journal articles
Open Access
Hydrogen peroxide and caustic soda: Dancing with a dragon while bleaching, TAPPI JOURNAL July 2013

Authors: Peter W. Hart; Carl Houtman; and Kilby Hirth | ABSTRACT: When hydrogen peroxide is mixed with caustic soda, an auto-accelerating reaction can lead to generation of significant amounts of heat and oxygen. On the basis of experiments using typical pulp mill process concentration and temperatures, a relatively simple kinetic model has been developed. Evaluation of these model results reveals that hydrogen peroxide-caustic soda systems are extremely sensitive to hydrogen peroxide:caustic soda ratio, transition metal contamination, and temperature. Small changes in initial conditions can result in a closed system becoming explosive. Analysis of model results was used to develop guidelines for safer application of hydrogen peroxide in a mill setting.

Journal articles
Open Access
Reducing aox by increasing oxidation potential in the first

ABSTRACT An increase in the standard oxidation potential of the reinforcing agent in the first caustic extraction stage will reduce the amount of AOX in the stage's effluent. A chlorinated broumstock pulp was treated alternatively in a basic caustic extraction (E) stage, an oxygen-reinforced caustic extraction (EO) stage, and an extraction stage reinforced with oxygen and peroxide (EOP). An AOX reduction of up to 30% was obtained in the effluent from the peroxide-reinforced extraction stage. In addition to the brownstock work, using two different model lignin compounds, we ran tests using oxyen, potassium permanganate, hydrogen peroxide with oxygen, and ozone with oxygen-reinforced caustic stages. In all cases, increasing the oxidation potential of the reinforcing agent decreased the amount of AOX detected in the effluent.

Journal articles
Open Access
Hydrogen peroxide and caustic soda: Dancing with a dragon while bleaching,TAPPI Journal December 2024

Peter W. Hart, Carl Houtman, and Kilby Hirth | TAPPI J. 12(7): 59(2013) - ABSTRACT: When hydrogen peroxide is mixed with caustic soda, an auto-accelerating reaction can lead to generation of significant amounts of heat and oxygen. On the basis of experiments using typical pulp mill process concentration and temperatures, a relatively simple kinetic model has been developed. Evaluation of these model results reveals that hydrogen peroxide-caustic soda systems are extremely sensitive to hydrogen peroxide:caustic soda ratio, transition metal contamination, and temperature. Small changes in initial conditions can result in a closed system becoming explosive. Analysis of model results was used to develop guidelines for safer application of hydrogen peroxide in a mill setting.

Journal articles
Open Access
Reducing aox by increasing oxidation potential in the first caustic extraction stage, TAPPI Journal December 2024

Authors: Peter W. Hart and Jeffrey S. Hsieh | Tappi J. 74(11): 117(1991) - ABSTRACT: An increase in the standard oxidation potential of the reinforcing agent in the first caustic extraction stage will reduce the amount of AOX in the stage's effluent. A chlorinated broumstock pulp was treated alternatively in a basic caustic extraction (E) stage, an oxygen-reinforced caustic extraction (EO) stage, and an extraction stage reinforced with oxygen and peroxide (EOP). An AOX reduction of up to 30% was obtained in the effluent from the peroxide-reinforced extraction stage. In addition to the brownstock work, using two different model lignin compounds, we ran tests using oxyen, potassium permanganate, hydrogen peroxide with oxygen, and ozone with oxygen-reinforced caustic stages. In all cases, increasing the oxidation potential of the reinforcing agent decreased the amount of AOX detected in the effluent.

Journal articles
Open Access
Production of high yield bleached hardwood kraft pulp: Breaking the kraft pulp yield barrier,TAPPI Journal December 2024

Author: Peter W. Hart | TAPPI J. 10(9): 37(2011) - ABSTRACT: A modified kraft pulping process has been developed that successfully breaks the traditional hard-wood kraft pulp yield barrier. The process produces fully bleached, high brightness hardwood kraft pulp with a yield of greater than 53% on wood. Details of the development and processing steps, along with various recovery cycle impacts, are discussed.