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Magazine articles
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Editor's Note: A Distinctive Name and Career, TAPPI JOURNAL

Editor's Note: A Distinctive Name and Career, TAPPI JOURNAL August 2011

Journal articles
Magazine articles
Open Access
Editor's Note: Great expectations, TAPPI JOURNAL January 201

Editor's Note: Great expectations, TAPPI JOURNAL January 2011

Journal articles
Magazine articles
Open Access
Discrete element method to model cracking for two layer systems, TAPPI Journal February 2019

Discrete element method to model cracking for two layer systems, TAPPI Journal February 2019

Journal articles
Magazine articles
Open Access
Cracking at the fold in double layer coated paper: the influence of latex and starch composition, TAPPI Journal February 2019

Cracking at the fold in double layer coated paper: the influence of latex and starch composition, TAPPI Journal February 2019

Journal articles
Magazine articles
Open Access
Magnetization of aminated lignin and characterization, TAPPI JOURNAL January 2019

Magnetization of aminated lignin and characterization, TAPPI JOURNAL January 2019

Journal articles
Magazine articles
Open Access
Synthesis and characterization of novel foams by pyrolysis of lignin, TAPPI Journal January 2019

Synthesis and characterization of novel foams by pyrolysis of lignin, TAPPI Journal January 2019

Journal articles
Magazine articles
Open Access
Prehydrolysis kraft pulping of jute cutting and caddis mixture for rayon production

ABSTRACT: Jute cutting, jute caddis, and cutting-caddis mixtures were prehydrolyzed by varying time and temperature to get about 90% prehydrolyzed yield. At the conditions of 170°C for 60 min of prehydrolysis, the yield for 100% jute cutting was 76.3%, while the same for jute caddis was only 67.9%. But with prehydrolysis at 150°C for 60 min, the yield was 90% for jute cutting, where 49.94% of original pentosan was dissolved and prehydrolysis of jute caddis at 140°C in 60 min yielded 86.4% solid residue. Jute cutting-caddis mixed prehydrolysis was done at 140°C for 30 min and yielded 92% solid residue for 50:50 cutting-caddis mixtures, where pentosan dissolution was only 29%. Prehydrolyzed jute cutting, jute caddis, and cutting-caddis mixtures were subsequently kraft cooked. Pulp yield was only 40.9% for 100% jute cutting prehydrolyzed at 170°C for 60 min, which was 10.9% lower than the prehydrolysis at 140°C. For jute cutting-caddis mixed prehydrolysis at 140°C for 45 min followed by kraft cooking, pulp yield decreased by 3.3% from the 100% cutting to 50% caddis in the mixture, but 75% caddis in the mixture decreased pulp yield by 6.7%. The kappa number 50:50 cutting-caddis mixture was only 11.3. Pulp bleachability improved with increasing jute cutting proportion in the cutting-caddis mixture pulp.

Journal articles
Magazine articles
Open Access
Research needs for nanocellulose commercialization and applications

INTRODUCTION: This short review deals with some applications and research needs for nanocellulosic (NC) materials; primarily cellulose nanocrystals (CNC), cellulose nanofibers (CNF), and bacterial cellulose (BC). Whereas CNC and BC materials are fairly homogenous, CNF materials represent a wide sector of different materials, often with a high heterogeneity. This is due to different pretreatment methods (mechanical, chemical, enzymatic), woodbased or agricultural-based materials, delignification and bleaching procedures, etc. The purpose of this comprehensive review is not to discuss the various production methods, for which the reader may consult with a selected number of reviews [1-6]; thus, the focus is on practical applications. Practical applications and potential markets were also discussed some years ago by other investigators [7-8]. Upscaling and choice of pretreatment methods, as well as economic considerations and different business models, have also been discussed, along with: œ Toxicity and environmental issues [9-10] œ The complex characterization of cellulose nanomaterials [4] The reader should also be aware of new contenders to the three classic groups of cellulosic nanomaterials, which are already in a commercial phase. These include cellulose filaments [11-12] and materials from mechanical grinding processes [13], and these materials may be nanostructures or not, depending on our classification. Finally, as indicated by the editorial on p. 275, scientists are currently taking a deep dive into the fundamental features of nanocellulosic materials [14-15].

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Open Access
Using bleaching stage models for benchmarking softwood ECF bleach plants, TAPPI Journal July 2022

ABSTRACT: Steady-state bleaching delignification and brightening models were used to gauge how well elemental chlorine-free (ECF) bleach plants were using chlorine dioxide to bleach 25-kappa softwood brownstocks. Case 1 examined the D0(EOP)D1 portion of Mill 1’s five-stage sequence that brightens the pulp to 86% ISO. Case 2 studied the D0(EO)D1 portion of Mill 2’s four-stage sequence, which brightens the pulp to 82% ISO, and Case 3 re-examined the same bleach plant several years after it made improvements around the extraction stage. The models highlighted days in the previously mentioned cases where high bleach usage occurred, presumably because of high brownstock and/or extraction washer carryover, and days where bleach usage was normal. In Case 2, the model esti-mated that 10 kg of the 44 kg chlorine dioxide/metric ton pulp consumed in bleaching was likely reacting with washer carryover sources; approximately two-thirds of this extra consumption was assumed to be reacting with extraction filtrate. Changes that Mill 2 made (Case 3) reduced the unproductive chlorine dioxide usage from 10 to 5 kg/metric ton pulp. When the delignification and brightening models were simultaneously solved, the models predicted somewhat different optimized distributions of chlorine dioxide to D0 and D1 vs. actual values used in bleach plants. However, the forecasted chlorine dioxide totals agreed with the actual values when washer carryover sources were considered. This study showed the bleaching models could be used as hypothetical benchmarks for softwood ECF bleach plants.

Journal articles
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Open Access
Water chemistry challenges in pulping and papermaking • fundamentals and practical insights: Part 1: Water chemistry fundamentals and pH, TAPPI Journal June 2022

ABSTRACT: Water is an essential component of the papermaking process. Nevertheless, papermakers often overlook its importance compared to fibers and chemical additives. A better understanding of water properties and chemical interactions associated with water at the wet end leads to a sound foundation for high-quality paper production and smooth operation. Not all fresh water and process water is the same. Fresh water varies from mill to mill, primarily due to the location and availability of water sources. Some industrial trends, such as enhancing water conservation and production yield, gradually shift process water quality over time. The current work serves as a primer on water and water chemistry fundamentals to help the papermaker prepare for the future challenges of increased contamination of process water associated with reduced fresh water usage. This paper focuses on basic water chemistry definitions and discusses the impact of pH on wet-end operation. It is clear that pH is a fundamental factor that directly affects the process and impacts other factors relevant to the papermaking process. It is crucial to understand what pH represents, how it is measured, how to select the proper pH and carefully control it, and how to closely maintain the process at target setpoints. Understanding the sensitivity of operation to pH change will lead to an appropriate focus on these issues. In addition to basic theory, we also review onsite experience and practical mill cases. It is imperative to stress that, although critical, pH is not the only chemical parameter impacting papermaking operations. Other factors, such as ionic concentration measured by conductivity, surface, soluble charge, and hardness, are critical and will be discussed in Part II of this series. As pH is a primary and independent factor that impacts various forms of charge and conductivity, the authors decided to start the current series of papers by discussing pH.