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A model black liquor formulation for use in development and evaluation of membranes for concentrating weak black liquor, TAPPI Journal February 2022
ABSTRACT: As part of a larger program to develop robust membranes for concentrating weak black liquor prior to the evaporation step, several commercially available membranes were tested for suitability in this application. Given the variation in kraft black liquor for various wood species, the mill-to-mill variations, and the challenges of obtaining fresh samples, the need became apparent for a synthetic reference black liquor that would allow any membrane developer to test a new prototype membrane and compare the results with others. We present a formulation for a model black liquor (MBL) similar to real kraft black liquor in the composition of the major species that can be formulated from readily available reagents. The MBL was tested with two commercial membranes and resulted in similar levels of lignin retention as the real black liquor. It also showed similar viscosity behavior to real black liquor as a function of solids content.
Journal articles
Magazine articles
Editorial: TAPPI Standards development: Authors and reviewers are welcome, TAPPI Journal July 2021
ABSTRACT: Readers of TAPPI Journal (TJ) and those involved with R&D and process and product quality will be familiar with TAPPI Standard Test Methods. These test methods are necessary for validating research and ensuring the quality of end products. In addition to test methods, TAPPI also publishes information that isn’t directly related to test methods, such as technical information and definitions, which include specifications, guidelines, and glossaries. All Standards information is developed with the consensus of a technical working group that adheres to set procedures.
Journal articles
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Lignin-based resins for kraft paper applications, TAPPI Journal November 2019
ABSTRACT: We investigated miscanthus (MS) and willow (W) lignin-furfural based resins as potential reinforce-ment agents on softwood and hardwood kraft paper. These resins might be sustainable alternatives to the commercial phenolformaldehyde (PF) resins. Phenol is a petrochemical product and formaldehyde has been classified as a carcinogen by the U.S. Environmental Protection Agency. The lignin used in this study was derived from hot water extraction (160ºC, 2 h) of MS and W biomass, and may be considered sulfur-free. These biorefinery lignins were characterized for their chemical composition and inherent properties via wet chemistry and instrumental techniques. The resin blends (MS-resin and W-resin) were characterized for their molecular weight, thermal behavior, and mechanical properties. Mechanical properties were measured by the resin’s ability to reinforce softwood and hard-wood kraft papers. The effect of adding hexamethylenetetramine (HMTA), a curing agent, to the resin was also examined. Mixtures of PF and lignin-based resins were investigated to further explore ways to reduce use of non-renewables, phenol, and carcinogenic formaldehyde. The results show that lignin-based resins have the potential to replace PF resins in kraft paper applications. For softwood paper, the highest strength was achieved using W-resin, without HMTA (2.5 times greater than PF with HMTA). For hardwood paper, MS-resin with HMTA gave the highest strength (2.3 times higher than PF with HMTA). The lignin-based resins, without HMTA, also yielded mechanical properties comparable to PF with HMTA.
Journal articles
Magazine articles
Using multistage models to evaluate how pulp washing after the first extraction stage impacts elemental chlorine-free bleach demand, TAPPI Journal November 2018
Using multistage models to evaluate how pulp washing after the first extraction stage impacts elemental chlorine-free bleach demand, TAPPI Journal November 2018
Journal articles
Magazine articles
Visual discrimination of hygiene tissue softness in the abse
Visual discrimination of hygiene tissue softness in the absence of haptic feedback, TAPPI JOURNAL August 2017
Journal articles
Magazine articles
How old are fibers in paper for recycling and what is their
How old are fibers in paper for recycling and what is their life expectancy? A contribution to the life cycle assessment of wood fiber-based products, TAPPI JOURNAL July 2017
Journal articles
Magazine articles
Accelerated aging of bio-oil from lignin conversion in subcr
Accelerated aging of bio-oil from lignin conversion in subcritical water, TAPPI JOURNAL March 2017
Journal articles
Magazine articles
Boosting the elongation potential of paper by mechanical refining and additives, TAPPI JOURNAL September 2018
Boosting the elongation potential of paper by mechanical refining and additives, TAPPI JOURNAL September 2018
Journal articles
Magazine articles
Structural analysis of poplar and Masson pine lignocresols and comparison of their bovine serum albumin adsorption characteristics, TAPPI JOURNAL January 2019
Structural analysis of poplar and Masson pine lignocresols and comparison of their bovine serum albumin adsorption characteristics, TAPPI JOURNAL January 2019
Journal articles
Magazine articles
Rheological characterization of tack and viscoelasticity of compositions of crepe coating used in the Yankee dryer, TAPPI Journal November 2019
ABSTRACT: The vast majority of tissue production uses creping to achieve the required set of properties on the base sheet. The Yankee coating helps to develop the desired crepe that in turn determines properties such as bulk and softness. The adhesion of the sheet to the Yankee surface is a very important characteristic to consider in achieving the desired crepe. The coating mix usually consists of the adhesive, modifier, and release. A good combination of these components is essential to achieving the desired properties of the tissue or towel, which often are determined by trials on the machine that can be time consuming and lead to costly rejects. In this paper, five compo-sitions of an industrial Yankee coating adhesive, modifier, and release were examined rheologically. The weight ratio of the adhesive was kept constant at 30% in all five compositions and the modifier and release ratios were varied. The normal force and work done by the different compositions have been shown at various temperatures simulating that of the Yankee surface, and the oscillatory test was carried out to explain the linear and nonlinear viscoelastic characteristic of the optimal coating composition.