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Editorial: A preview of PEERS 2019, TAPPI Journal September 2019
ABSTRACT: Coming soon is PEERS • TAPPI’s annual Pulping, Engineering, Environmental, Recycling and Sustainability gathering for industry professionals. Held this October 27-30 in St. Louis, MO, the conference is co-located with the International Bioenergy & Bioproducts Conference (IBBC) and the 12th Research Forum on Recycling. Universities and research organizations from around the world are represented in the conference content, and below is a sampling of just a few of the many presentations that might interest TAPPI Journal readers.
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Characterization of chia plant (Salvia hispanica) for pulping, TAPPI Journal October 2020
ABSTRACT: In this paper, chia plant was characterized in terms of chemical, morphological, and anatomical properties. Chia plant was characterized with low a-cellulose (30.5%); moderate lignin (23.2%) with syringyl to guaiacyl ratio of 1.41; and shorter fiber length (0.67 mm) with thinner cell wall (1.91 µm) and good flexibility coefficient (71.44). Anatomical features showed that chia plant consists of vessels, fibers, parenchyma cells, and collenchyma cells. Chia plant pulping was evaluated in soda-anthraquinone (soda-AQ) and formic acid/peroxyformic acid (FA/PFA) processes. Chia plant was difficult to delignify in the alkaline process. The FA/PFA process produced higher pulp yield at the same kappa number than the soda-AQ process. Unbleached soda-AQ chia pulp exhibited good properties in terms of tensile, bursting, and tearing strengths, even at the unrefined stage, due to high drainability of the pulps. Alkaline peroxide bleached FA/PFA pulp exhibited better papermaking properties and 2% higher brightness than the D0(EP)D1 bleached soda-AQ pulp.
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Discrete element method to predict coating failure mechanisms, TAPPI JOURNAL January 2018
Discrete element method to predict coating failure mechanisms, TAPPI JOURNAL January 2018
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Quantification of vegetable oil in recycled paper, TAPPI JOURNAL September 2020
ABSTRACT: Vegetable soybean oil is commonly used in cooking foods that are packaged in takeaway paper-board containers. Vegetable oil is hydrophobic, and in sufficiently high concentration, could interfere with interfiber bonding and result in paper strength loss. In order to quantify the effect of oil on the resulting paperboard strength, it is necessary to quantify the oil content in paper. A lab method was evaluated to determine the soybean oil content in paper. Handsheets were made with pulps previously treated with different proportions of vegetable oil. Pyrolysis gas chromatography-mass spectrometry (pyGCMS) was used to quantify the amount of oil left in the handsheets. The results revealed a strong correlation between the amount of oil applied to the initial pulp and the amount of oil left in the handsheets.In addition, the effect of vegetable oils on paper strength may be affected by the cooking process. Vegetable oil is known to degrade over time in the presence of oxygen, light, and temperature. The vegetable oil was put in an oven to imitate the oil lifecycle during a typical pizza cooking process. The cooked oil was then left at room temperature and not protected from air (oxygen) or from normal daylight. The heated, then cooled, oil was stored over a period of 13 weeks. During this time, samples of the aged oil were tested as part of a time-based degradation study of the cooked and cooled oil.
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Recycling performance of softwood and hardwood unbleached kraft pulps for packaging papers, TAPPI Journal February 2023
ABSTRACT: The scope of this work is to evaluate the recyclability potential of hardwood and softwood unbleached kraft pulps, leading to a sound basis for comparison and even to support a decision about fibers accord-ing to the performance achieved. The influence of successive recycling cycles (up to 10 cycles) on the fiber morphol-ogy, pulp suspension drainability, water retention capacity, and handsheet mechanical properties were studied for Eucalyptus globulus and Pinus sylvestris unbleached kraft pulps. The performance of these pulps as linerboard and corrugating medium for packaging was also evaluated. The requirements for brown kraftliner and for high perfor-mance recycled fluting grades is preserved for E. globulus pulp during all 10 recycling cycles, evidenced by the mod-erate decrease of burst index and crush resistance index and by the short-span compression index, whereas the P. sylvestris pulp loses this rating after the second cycle. These results strongly support the higher performance of E. globulus pulp for recycling as compared with softwood kraft pulp from the perspective of packaging papers.
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Chemical addition to wet webs using foam application, TAPPI Journal January 2023
ABSTRACT: In papermaking, the conventional way to add chemicals to the web is to dose them into the fiber stock and form the paper afterwards. However, in many cases, adding chemicals directly to the stock is challenging. For example, strength aids tend to increase flocculation in the stock, which limits the addition amounts of those aids. The need for better performance of paper (and paperboard) products has given rise to the need for functionalization of paper. Adding such functional chemicals to the stock is usually rather inefficient. Hence, novel methods are needed to add chemicals to the paper bulk. One such method is dosing chemicals to the wet web via foam application. In this study, we built a laboratory-scale sheetfed dynamic foam application device and utilized it to study addition of starch to wet bleached chemithermomechanical pulp (BCTMP) paper handsheets. The impact of parameters such as vacuum level, the amount of added chemical, and the viscosity of the foaming liquid on the penetration of starch into the wet web was explored. Starch penetration into wet webs was measured via iodine-potassium iodide staining, followed by image analysis. According to our results, controlling the viscosity of the foaming liquid gives the best possibility to control the penetration.
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Dielectric spectroscopic studies of biological material evolution and application to paper, TAPPI JOURNAL September 2018
Dielectric spectroscopic studies of biological material evolution and application to paper, TAPPI JOURNAL September 2018
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Progress in foam forming technology, TAPPI JOURNAL August 2019
ABSTRACT: This paper summarizes recent developments in foam forming that were mainly carried out in pilot scale. In addition to improving the efficiency of existing processes and allowing better uniformity in material, a wide variety of raw materials can be utilized in foam forming. The focus of this paper is thin webs—papers, boards and foam-laid nonwovens, along with the pilot scale results obtained at VTT in Finland. For paper and board grades, the most direct advantage of foam forming is the potential to produce very uniform webs from longer and coarser fibers and obtain material savings through that. Another main point is increased solids content after a wet press, which may lead to significant energy savings in thermal drying. Finally, the potential to introduce “difficult” raw materials like long synthetic or manmade fibers into a papermaking process enables the manufacturing of novel products in an existing production line. This paper also briefly discusses other interesting foam-based applications, including insulation and absorbing materials, foam-laid nonwovens, and materials for replacing plastics.
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The sticky behavior of pulp and paper mill biosludge during drying, TAPPI Journal June 2019
ABSTRACT: Pulp and paper mill biosludge becomes sticky after being dried to a certain solids content. As bio-sludge becomes sticky, it agglomerates and adheres to the heat transfer surfaces of the dryer. This undesirable property can lower the dryer efficiency and cause the drying equipment to fail.A systematic study was conducted to examine the sticky behavior of biosludge. The stickiness was evaluated by measuring the adhesive force between a sludge cake and a stainless steel substrate, and the cohesive force between a sludge cake and a sludge substrate. The results show that: i) both adhesive and cohesive forces increase markedly as the solids content increases, reaching a maximum value at about 13% solids, and then decrease steadily at a high-er solids content; ii) cohesive force is stronger than adhesive force, implying that biosludge tends to agglomerate rather than adhere to smooth equipment surfaces; and iii) mixing wood fines or fly ash from a biomass boiler reduc-es the stickiness of the mixture. These findings may help mills improve the thermal efficiency of biosludge dryers and to turn biosludge into a more attractive fuel for burning in biomass boilers.
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Fabrication of cross-linked starch-based nanofibrous mat with optimized diameter, TAPPI JOURNAL June 2019
ABSTRACT: The design and synthesis of natural and synthetic polymer blends have received recent and wide attention. These new biomaterials exhibit progress in properties required in the field of medicine and healthcare. Herein, the aim of present study is to fabricate starch (ST)/polyacrylic acid (PAA) electrospun nanofibrous mat with a smooth and uniform morphology, lowest fiber diameter (below 100 nm) and the highest possible starch content. Starch itself is poor in process-ability, and its electrospinning could be quite a challenging process. To address this, we carried out the response surface methodology (RSM) technique for modelling the electrospinning process. In order to have ST/PAA nanofibers with the finest possible diameter, optimized processing parameters (applied volt-age, nozzle-collector distance and feed rate) obtained from RSM technique were applied. ST/PAA electrospun nano-fibers with an average diameter of 74±13 nm were successfully achieved via the electrospinning method for the first time. The structure, preparation and properties of the nanofibrous structure were discussed. Results indicated that drug loaded ST/PAA blend nanofibrous structure has a great potential to be used in controlled drug release systems.