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Furnishing autohydrolyzed poplar weakly alkaline P-RC APMP to make lightweight coated base paper, TAPPI Journal February 2022
ABSTRACT: This work investigated the effects of autohydrolysis pretreatment severity on poplar (Populus tomentosa Carr.) woodchips used to make a type of high-yield pulp (HYP) known as preconditioning followed by refiner chemical treatment, alkaline peroxide mechanical pulp (P-RC APMP). It also investigated the ratios for partially replacing sodium hydroxide (NaOH) with magnesium oxide (MgO) in the high-consistency (HC) retention stage of the P-RC APMP process on the obtained HYP’s properties. The results show that the pretreatment severity of autohydrolysis at combined hydrolysis factor (CHF) = 10.77 and the 50 wt% ratio for partially substituting NaOH with MgO were the optimum conditions for making light-weight coated (LWC) base paper. Compared to the conventional P-RC APMP, the optimized P-RC APMP had similar bulk and higher tensile, burst, and tear indices, as well as opacity, but a slightly lower ISO brightness. When the optimized P-RC APMP and commercial softwood bleached sulfate pulp (SBKP) were blended to make LWC base paper, the most favorable pulp furnish was comprised of 50% optimized P-RC APMP and 50% commercial SBKP. The obtained LWC base paper handsheet had better bulk, and its other properties could also meet the require-ments of LWC base paper.
Journal articles
Magazine articles
The Shendye-Fleming OBA Index for paper and paperboard, TAPPI Journal March 2022
ABSTRACT: We are proposing a new one-dimensional scale to calculate the effects of optical brightening agents (OBA) on the bluish appearance of paper. This index is separate from brightness and whiteness indices.In the paper industry, one-dimensional scales are widely used for determining optical properties of paper and paperboard. Whiteness, tint, brightness, yellowness, and opacity are the most common optical properties of paper and paperboard. Most of the papers have a blue cast generated by addition of OBA or blue dyes. This blue cast is given because of the human perception that bluer is whiter, up to a certain limit. To quantify this effect, it is necessary to determine how much blue cast paper and paperboard have. As the printing industry follows the ISO 3664 Standard for viewing, which has a D50 light source, this also plays a very important role in showing a blue cast. Color perception is based on light source and light reflected from an object. The ultraviolet (UV) component in D50 interacts with OBA to provide a reflection in the blue region of the visible spectrum. Use of a UV blocking filter results in measurements without the effect of emission in the blue region. This difference is used in determining the OBA effect in the visible range of the paper. This equation is known as the Shendye-Fleming OBA Index.
Journal articles
Controllable conversion of cellulose nanocrystals to cellulose microspheres: Insight on the effect of parameters during spray drying, TAPPI Journal February 2025
ABSTRACT: Cellulose microspheres, which have mainly been produced via the sol-gel method up until now, exhibit a promising potential for broad applications due to their regular microstructure and renewability. However, some issues with production of cellulose microspheres, such as the recycling of involved organic solvents and the removal of the residual solvents, should be solved. In this study, a cellulose nanocrystals (CNCs) suspension was used to produce cellulose microspheres via spray drying in order to avoid the use of organic solvents. The effects of CNCs particle size, CNCs concentration, and inlet temperature of spray drying on microstructure and particle size of cellulose microspheres were investigated. The results indicated that the optimal average particle size and concentration of CNCs used for obtaining cellulose microspheres were 106 nm and 0.1 wt%, respectively. Under the optimal conditions, cellulose microspheres with a regular spherical morphology and an average particle size of ca. 3 ìm were obtained. The sulfuric acid hydrolysis and spray drying process barely affected the crystalline structure of cellulose. However, the introduced sulfhydryl groups, which were confirmed by Fourier transform infrared spectroscopy results, degraded the thermostability of cellulose. Generally speaking, converting CNCs to cellulose microspheres via spray drying is beneficial for promoting the controllable and continuous production of cellulose microspheres.
Journal articles
Data-efficient determination of machine-specific process windows in thermoforming using the example of PCR materials, TAPPI Journal July 2025
ABSTRACT: In an industrial context, process windows for thermoplastics in thermoforming processes are still often determined through time-consuming trial-and-error approaches. This results in increased effort when commissioning new machines, implementing new technologies, or substituting sheet materials. One key reason is the lack of methods that allow for efficient, process-related assessment of material behavior and a quantitative definition of a “target state” of the heated sheet in relation to geometry and process conditions. In this study, we present the In-Situ Thermoforming Characterization (ITC) method as an application-oriented approach that enables format-independent evaluation of material behavior directly within the forming station of a thermoforming system. The method was successfully applied to a material substitution case, replacing conventional virgin polypropylene (PP) with post-consumer recyclate (PCR) — in this case, recycled PP (rPP) — in the production of a defined cup geometry. The results enabled the transfer of existing process knowledge from the virgin material to the recyclate, thereby accelerating material qualification. Based on the collected data, material behavior under process conditions could be mapped within the design space, making it possible to identify machine settings that deliver equivalent forming results in our test setup. Overall, the method shows strong potential for efficient and precise determination of machine-specific process windows.
Journal articles
Magazine articles
Sulfur makeup in an unbleached kraft pulp mill, TAPPI Journal August 2024
ABSTRACT: Sodium sesquisulfate or “sesqui” (Na3H(SO4)2) is a by-product of chlorine dioxide production at kraft pulp mills. It is typically used for sodium and sulfur makeup in the liquor loop. Mondi Hinton Inc. (MHI) in Hinton, AB, Canada, was converting from bleached to unbleached kraft pulp production and was thus losing this source of makeup. The only option that was readily available as a substitute was sodium hydrosulfide (NaHS), which was cost prohibitive. Other options such as sodium sulfate (Na2SO4), emulsified sulfur, sulfuric acid (H2SO4), and sodium bisulfite (NaHSO3) were compared. The mill concluded that pelletized sulfur plus sodium hydroxide or “caustic soda” (NaOH) was the best option. Laboratory-scale experiments showed that pelletized sulfur dissolved in white liquor (WL). A mill-scale trial revealed that pelletized sulfur added to a causticizer had no adverse impacts on the downstream pressure filters or kiln operation. The sulfur reacted to produce polysulfide upstream of the WL storage tank, giving the liquor an orange hue. This polysulfide appeared to partially degrade into thiosulfate before being fed to the digester. The heavy black liquor (HBL) sulfur:sodium (S:Na) ratio did not change significantly, even though the sulfur/soda addition location was upstream of the original one. In addition, other properties such as liquor heating value and elemental analysis did not significantly change. Due to polysulfide/thiosulfate concentration in the white liquor, it was determined that the carbon steel equipment was at risk for corrosion. During the annual turnaround that occurred eight months after the addition of sulfur was started, the wash zone of the digester showed no signs of thinning/damage. The mill has been running exclusively with pelletized sulfur for 22 months (as of August 2024), realizing significant cost savings compared to the use of NaHS or other sulfur/soda addition options.
Journal articles
Magazine articles
The role of hornification in the deterioration mechanism of physical properties of unrefined eucalyptus fibers during paper recycling, TAPPI Journal February 2024
ABSTRACT: Physical properties of cellulosic paper deteriorate significantly during paper recycling, which hinders the sustainable development of the paper industry. This work investigates the property deterioration mechanism and the role of hornification in the recycling process of unrefined eucalyptus fibers. The results showed that during the recycling process, the hornification gradually deepened, the fiber width gradually decreased, and the physical properties of the paper also gradually decreased. After five cycles of reuse, the relative bonding area decreased by 17.6%, while the relative bonding force decreased by 1.8%. Further results indicated that the physical property deterioration of the paper was closely related to the decrease of fiber bonding area. The fiber bonding area decreased linearly with the reduction of re-swollen fiber width during paper recycling. Re-swollen fiber width was closely related to the hornification. Hornification mainly reduces the bonding area of unrefined eucalyptus fiber rather than the bonding force. The work elucidates the role of hornification in the recycling process of unrefined eucalyptus fibers and the deterioration mechanism of paper physical properties, which will be helpful to control the property deterioration of paper and achieve a longer life cycle.
Journal articles
Magazine articles
The Paper360° 2020 TOP 50 POWER LIST, Paper360º July/August 2020
The Paper360° 2020 TOP 50 POWER LIST, Paper360º July/August 2020
Journal articles
Magazine articles
Understanding extensibility of paper: Role of fiber elongation and fiber bonding, TAPPI Journal March 2020
ABSTRACT: The tensile tests of individual bleached softwood kraft pulp fibers and sheets, as well as the micro-mechanical simulation of the fiber network, suggest that only a part of the elongation potential of individual fibers is utilized in the elongation of the sheet. The stress-strain curves of two actual individual pulp fibers and one mimicked classic stress-strain behavior of fiber were applied to a micromechanical simulation of random fiber networks. Both the experimental results and the micromechanical simulations indicated that fiber bonding has an important role not only in determining the strength but also the elongation of fiber networks. Additionally, the results indicate that the shape of the stress-strain curve of individual pulp fibers may have a significant influence on the shape of the stress-strain curve of a paper sheet. A large increase in elongation and strength of paper can be reached only by strengthening fiber-fiber bonding, as demonstrated by the experimental handsheets containing starch and cellulose microfibrils and by the micromechanical simulations. The key conclusion related to this investigation was that simulated uniform inter-fiber bond strength does not influence the shape of the stress-strain curve of the fiber network until the bonds fail, whereas the number of bonds has an influence on the activation of the fiber network and on the shape of the whole stress-strain curve.
Journal articles
Magazine articles
Kraft pulp viscosity as a predictor of paper strength: Its uses and abuses, TAPPI Journal October 2023
ABSTRACT: For bleached kraft pulps, two factors govern paper strength: the individual fiber strength, and the bond strength that adheres the individual fibers together in the paper matrix. Inherent fiber strength is related to the length of the carbohydrate polymers, also known as the degree of polymerization (DP). Average DP (DP) is inferred by performing pulp viscosity measurements. Under certain circumstances during kraft pulping and bleaching, the average polymer lengths can be shortened, resulting in lower pulp viscosity, and may indicate fiber damage. Fiber damage typically manifests itself as a reduction in tear strength for well-bonded handsheets.This paper will review the literature on how pulp viscosity can predict paper/fiber strength and how it can be used as a diagnostic tool. It can be a means to monitor pulp quality during pulping and bleaching, as well as to alert when such operations approach a critical threshold. However, viscosity losses must be carefully and judiciously analyzed. Like most diagnostic tools, viscosity measurements can be misused and abused, which can lead to incorrect inferences about intrinsic fiber strength. This review will also cover these misuses. The overall goal is to provide the papermaker a better understanding of what pulp viscosity is, how it correlates to potential sheet strength, and what its limitations are. It will be illustrated that when pulp viscosity drops below a critical value, it will indicate an appreciable deterioration in the paper’s tear and tensile strength.
Journal articles
Magazine articles
Filtration efficiency and breathability of selected face masks, TAPPI Journal September 2023
ABSTRACT: Face masks have been used as physical barriers to stop respiratory infections for many years. Due to insufficient and low supply of certified masks, alternative face covers such as face shields, neck gaiters, and fabric reusable masks gained attention during the COVID-19 pandemic. However, for these alternate face masks to fulfill their intended function, they must be effective. Additionally, the level of breathability provided by the makeshift masks must be at a certain level. The work reported in this paper was carried out to determine the relationship between filtration efficiency (FE), breathability, and important physical characteristics of mask substrates. The fiber diameter of the core filter layer was determined using a scanning electron microscope. Five types of face masks (two types of N95, two types of surgical masks, and a 100% knitted cotton fabric) were tested for their FE and breathability using moisture vapor transmission rate (MVTR). The cotton knitted mask had the lowest FE (5.10%•26.47%), while the National Institute for Occupational Safety and Health (NIOSH)-certified N95 mask had the highest FE values (92.10%•99.65%). However, the cotton mask outperformed the N95 in terms of the pressure drop, meaning higher comfort. In general, the N95 face mask provided the best protection against aerosolized particles. According to the regression analysis, the fiber diameter of the mask filter substrate serves as an important predictor of FE of mask substrates. In this study, it was confirmed that fiber diameter is inversely related to the filtration ability. Results show that compact structure with finer fibers will enable higher filtration efficiency. The study lends itself to developing layered face masks to obtain optimum filters with good filtration, better fit, and acceptable comfort for the wearer.